Functionalization of P4 in the coordination sphere of coinage metal cations

Jaap E. Borger; Martijn S. Bakker; Andreas W. Ehlers; Martin Lutz; J. Chris Slootweg; Koop Lammertsma

doi:10.1039/C5CC10037B

Functionalization of P4 in the coordination sphere of coinage metal cations

Jaap E. Borger, Martijn S. Bakker, Andreas W. Ehlers, Martin Lutz, J. Chris Slootweg, Koop Lammertsma

University of Amsterdam

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η2–P4 complexes. This novel approach allows controlled P–C bond formation using the bulky DmpLi (Dmp = 2,6-Mes2C6H3) and the unencumbered MesLi, giving sterically diverse doubly complexed RP4 butterfly derivatives in a single step.

Original language	English
Pages (from-to)	3284-3287
Journal	Chemical Communications
Volume	52
Issue number	16
DOIs	https://doi.org/10.1039/C5CC10037B
Publication status	Published - 2016

Access to Document

10.1039/C5CC10037B

FunctionalizationFinal published version, 1.89 MB

http://xlink.rsc.org/?DOI=C5CC10037B

Cite this

@article{130d7bf037914941a5e1c2067dbff225,

title = "Functionalization of P4 in the coordination sphere of coinage metal cations",

abstract = "Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η2–P4 complexes. This novel approach allows controlled P–C bond formation using the bulky DmpLi (Dmp = 2,6-Mes2C6H3) and the unencumbered MesLi, giving sterically diverse doubly complexed RP4 butterfly derivatives in a single step.",

author = "Borger, {Jaap E.} and Bakker, {Martijn S.} and Ehlers, {Andreas W.} and Martin Lutz and {Chris Slootweg}, J. and Koop Lammertsma",

year = "2016",

doi = "10.1039/C5CC10037B",

language = "English",

volume = "52",

pages = "3284--3287",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - Functionalization of P4 in the coordination sphere of coinage metal cations

AU - Borger, Jaap E.

AU - Bakker, Martijn S.

AU - Ehlers, Andreas W.

AU - Lutz, Martin

AU - Chris Slootweg, J.

AU - Lammertsma, Koop

PY - 2016

Y1 - 2016

N2 - Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η2–P4 complexes. This novel approach allows controlled P–C bond formation using the bulky DmpLi (Dmp = 2,6-Mes2C6H3) and the unencumbered MesLi, giving sterically diverse doubly complexed RP4 butterfly derivatives in a single step.

AB - Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η2–P4 complexes. This novel approach allows controlled P–C bond formation using the bulky DmpLi (Dmp = 2,6-Mes2C6H3) and the unencumbered MesLi, giving sterically diverse doubly complexed RP4 butterfly derivatives in a single step.

U2 - 10.1039/C5CC10037B

DO - 10.1039/C5CC10037B

M3 - Article

SN - 1359-7345

VL - 52

SP - 3284

EP - 3287

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Functionalization of P4 in the coordination sphere of coinage metal cations

Abstract

Access to Document

Fingerprint

Cite this