First hyperpolarizability of CdS nanoparticles studied by hyper-Rayleigh scattering

B. S. Santos, G. A. L. Pereira, D. V. Petrov, C. de Mello Donegá

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

The first hyperpolarizability of nanocrystalline CdS particles (mean diameters of 2.0, 5.6 and 9.1 nm) was measured by the hyper-Rayleigh scattering technique. The results show that the first hyperpolarizability per CdS pair increases with decreasing particle size. This is ascribed to quantum confinement effects on the oscillator strengths. These effects lead to an enhancement by one order of magnitude in the first hyperpolarizability of 2 nm CdS particles, in comparison with bulk CdS.
Original languageEnglish
Pages (from-to)187-192
JournalOptics Communications
Volume178
Issue number1
DOIs
Publication statusPublished - 2000
Externally publishedYes

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