Evolution of microporosity and permeability of quartzofeldspathic rocks during changes in crustal conditions and tectonite fabric

Most crustal rocks contain some microporosity that can host fluids and allow them to permeate, which in turn impacts their physical properties and rheology. Using electron microscopic methods we have examined the nature
of microporosity in quartzofeldspathic rocks recovered from surface outcrops and boreholes that are representative of those actively deforming at up to 35km depth beneath New Zealand’s Southern Alps. In these exhumed samples
the main types of microporosity are: (i) dilatant grain boundaries, (ii) grain boundary dislocation etch pits, (iii) intragranular fluid inclusions of various types, (iv) dilatant sites on phyllosilicate basal planes. We observe changes
in the distribution and nature of porosity with proximity to the mylonitic shear zone down-dip of the active Alpine Fault, and these may be related to changes in the nature of the tectonite fabric. Our measurements of anisotropy of experimentally measured electrical conductivity and elastic wave propagation, and its change with increasing confining pressure (Pconf), provide insights into the relationship of microfracture porosity and mineral orientation. For example, electrical and elastic wave anisotropy (ρk/ρ⊥ and vpk/vp⊥) is high but decreases rapidly with increasing Pconf in samples with the strongest foliations, comprising foliation domains of quartz+feldspar with planar and through going phyllosilicate microlithons. Conversely, most weakly foliated samples where the same phases are well-mixed are less anisotropic and display less change in electrical and elastic wave anisotropy with increasing Pconf. This suggests linked type (iv) pore spaces parallel to foliation, which can host saline fluids, are preferentially closed with increasing Pconf. These types of changes are likely to only be significant at low Pconf, i.e., brittle conditions. At greater depth, in the creeping part of the shear zone, changes in the geometric arrangement of microporosity are more likely to result from differential thermal expansion and/or fluid-rock interactions. The TESA toolbox (https://umaine.edu/mecheng/vel/software/tesa_toolbox/) allows us to predict how thermal contraction may yield anisotropic grain boundary porosity for real microstructures. We can then validate these predictions by relating evidence of limited fluid-rock reactions to equilibrium phase diagrams for real bulk compositions.