Evolution of Fe species during the synthesis of over-exchanged Fe/ZSM5 obtained by chemical vapor deposition of FeCl3

AA Battiston; JH Bitter; FMF de Groot; AR Overweg; O Stephan; JA van Bokhoven; PJ Kooyman; C van der Spek; G Vanko; DC Koningsberger

doi:10.1016/S0021-9517(02)00051-9

Evolution of Fe species during the synthesis of over-exchanged Fe/ZSM5 obtained by chemical vapor deposition of FeCl3

AA Battiston, JH Bitter, FMF de Groot, AR Overweg, O Stephan, JA van Bokhoven, PJ Kooyman, C van der Spek, G Vanko, DC Koningsberger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The evolution of iron in over-exchanged Fe/ZSM5 prepared via chemical vapor deposition of FeCl3 was studied at each stage of the synthesis. Different characterization techniques (EXAFS, HR-XANES, Fe-57 Mossbauer spectroscopy, Al-27 NMR, EELS, HR-TEM, XRD, N-2 physisorption, and FTIR spectroscopy) were applied in order to correlate the changes occurring in the local environment of the Fe atoms with migration and aggregation phenomena of iron at micro- and macroscopic scale. Mononuclear isolated Fe-species are formed upon FeCl3 sublimation, which are transformed into binuclear Fe-complexes during washing. During calcination, iron detached from the Bronsted sites migrates to the external surface of the zeolite, finally leading to significant agglomeration. Nevertheless, agglomeration of Fe can be strongly suppressed by adequately tuning the conditions of the calcination. (C) 2002 Elsevier Science (USA). All rights reserved.

Original language	English
Article number	PII S0021-9517(02)00051-9
Pages (from-to)	251-271
Number of pages	21
Journal	Journal of Catalysis
Volume	213
Issue number	2
DOIs	https://doi.org/10.1016/S0021-9517(02)00051-9
Publication status	Published - 25 Jan 2003

Keywords

Fe/ZSM5
binuclear
iron
synthesis
evolution
calcination
X-RAY-ABSORPTION
SELECTIVE CATALYTIC REDUCTION
STATE ION-EXCHANGE
FINE-STRUCTURE
NOX REDUCTION
ADSORPTION COMPLEXES
EXAFS SPECTROSCOPY
FE-ZSM-5 CATALYSTS
XAFS SPECTROSCOPY
FE/MFI CATALYSTS

Access to Document

10.1016/S0021-9517(02)00051-9

J
Open Access (free)
Final published version, 736 KB

Cite this

Battiston, AA., Bitter, JH., de Groot, FMF., Overweg, AR., Stephan, O., van Bokhoven, JA., Kooyman, PJ., van der Spek, C., Vanko, G., & Koningsberger, DC. (2003). Evolution of Fe species during the synthesis of over-exchanged Fe/ZSM5 obtained by chemical vapor deposition of FeCl3. Journal of Catalysis, 213(2), 251-271. Article PII S0021-9517(02)00051-9. https://doi.org/10.1016/S0021-9517(02)00051-9

@article{c25c9bbb75d34ae2a400afcbe8227ff4,

title = "Evolution of Fe species during the synthesis of over-exchanged Fe/ZSM5 obtained by chemical vapor deposition of FeCl3",

abstract = "The evolution of iron in over-exchanged Fe/ZSM5 prepared via chemical vapor deposition of FeCl3 was studied at each stage of the synthesis. Different characterization techniques (EXAFS, HR-XANES, Fe-57 Mossbauer spectroscopy, Al-27 NMR, EELS, HR-TEM, XRD, N-2 physisorption, and FTIR spectroscopy) were applied in order to correlate the changes occurring in the local environment of the Fe atoms with migration and aggregation phenomena of iron at micro- and macroscopic scale. Mononuclear isolated Fe-species are formed upon FeCl3 sublimation, which are transformed into binuclear Fe-complexes during washing. During calcination, iron detached from the Bronsted sites migrates to the external surface of the zeolite, finally leading to significant agglomeration. Nevertheless, agglomeration of Fe can be strongly suppressed by adequately tuning the conditions of the calcination. (C) 2002 Elsevier Science (USA). All rights reserved.",

keywords = "Fe/ZSM5, binuclear, iron, synthesis, evolution, calcination, X-RAY-ABSORPTION, SELECTIVE CATALYTIC REDUCTION, STATE ION-EXCHANGE, FINE-STRUCTURE, NOX REDUCTION, ADSORPTION COMPLEXES, EXAFS SPECTROSCOPY, FE-ZSM-5 CATALYSTS, XAFS SPECTROSCOPY, FE/MFI CATALYSTS",

author = "AA Battiston and JH Bitter and \{de Groot\}, FMF and AR Overweg and O Stephan and \{van Bokhoven\}, JA and PJ Kooyman and \{van der Spek\}, C and G Vanko and DC Koningsberger",

year = "2003",

month = jan,

day = "25",

doi = "10.1016/S0021-9517(02)00051-9",

language = "English",

volume = "213",

pages = "251--271",

journal = "Journal of Catalysis",

issn = "0021-9517",

publisher = "Academic Press Inc.",

number = "2",

}

Battiston, AA, Bitter, JH, de Groot, FMF, Overweg, AR, Stephan, O, van Bokhoven, JA, Kooyman, PJ, van der Spek, C, Vanko, G & Koningsberger, DC 2003, 'Evolution of Fe species during the synthesis of over-exchanged Fe/ZSM5 obtained by chemical vapor deposition of FeCl3', Journal of Catalysis, vol. 213, no. 2, PII S0021-9517(02)00051-9, pp. 251-271. https://doi.org/10.1016/S0021-9517(02)00051-9

TY - JOUR

T1 - Evolution of Fe species during the synthesis of over-exchanged Fe/ZSM5 obtained by chemical vapor deposition of FeCl3

AU - Battiston, AA

AU - Bitter, JH

AU - de Groot, FMF

AU - Overweg, AR

AU - Stephan, O

AU - van Bokhoven, JA

AU - Kooyman, PJ

AU - van der Spek, C

AU - Vanko, G

AU - Koningsberger, DC

PY - 2003/1/25

Y1 - 2003/1/25

N2 - The evolution of iron in over-exchanged Fe/ZSM5 prepared via chemical vapor deposition of FeCl3 was studied at each stage of the synthesis. Different characterization techniques (EXAFS, HR-XANES, Fe-57 Mossbauer spectroscopy, Al-27 NMR, EELS, HR-TEM, XRD, N-2 physisorption, and FTIR spectroscopy) were applied in order to correlate the changes occurring in the local environment of the Fe atoms with migration and aggregation phenomena of iron at micro- and macroscopic scale. Mononuclear isolated Fe-species are formed upon FeCl3 sublimation, which are transformed into binuclear Fe-complexes during washing. During calcination, iron detached from the Bronsted sites migrates to the external surface of the zeolite, finally leading to significant agglomeration. Nevertheless, agglomeration of Fe can be strongly suppressed by adequately tuning the conditions of the calcination. (C) 2002 Elsevier Science (USA). All rights reserved.

AB - The evolution of iron in over-exchanged Fe/ZSM5 prepared via chemical vapor deposition of FeCl3 was studied at each stage of the synthesis. Different characterization techniques (EXAFS, HR-XANES, Fe-57 Mossbauer spectroscopy, Al-27 NMR, EELS, HR-TEM, XRD, N-2 physisorption, and FTIR spectroscopy) were applied in order to correlate the changes occurring in the local environment of the Fe atoms with migration and aggregation phenomena of iron at micro- and macroscopic scale. Mononuclear isolated Fe-species are formed upon FeCl3 sublimation, which are transformed into binuclear Fe-complexes during washing. During calcination, iron detached from the Bronsted sites migrates to the external surface of the zeolite, finally leading to significant agglomeration. Nevertheless, agglomeration of Fe can be strongly suppressed by adequately tuning the conditions of the calcination. (C) 2002 Elsevier Science (USA). All rights reserved.

KW - Fe/ZSM5

KW - binuclear

KW - iron

KW - synthesis

KW - evolution

KW - calcination

KW - X-RAY-ABSORPTION

KW - SELECTIVE CATALYTIC REDUCTION

KW - STATE ION-EXCHANGE

KW - FINE-STRUCTURE

KW - NOX REDUCTION

KW - ADSORPTION COMPLEXES

KW - EXAFS SPECTROSCOPY

KW - FE-ZSM-5 CATALYSTS

KW - XAFS SPECTROSCOPY

KW - FE/MFI CATALYSTS

U2 - 10.1016/S0021-9517(02)00051-9

DO - 10.1016/S0021-9517(02)00051-9

M3 - Article

SN - 0021-9517

VL - 213

SP - 251

EP - 271

JO - Journal of Catalysis

JF - Journal of Catalysis

IS - 2

M1 - PII S0021-9517(02)00051-9

ER -

Evolution of Fe species during the synthesis of over-exchanged Fe/ZSM5 obtained by chemical vapor deposition of FeCl3

Abstract

Keywords

Access to Document

Fingerprint

Cite this