Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments

Patrick O'Leary; C.A. van Walree; N.C. Mehendale; J. Summerel; D.E. Morse; G. van Koten; R.J.M. Klein Gebbink

Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments

Patrick O'Leary
, C.A. van Walree
, N.C. Mehendale
, J. Summerel
, D.E. Morse
, G. van Koten
, R.J.M. Klein Gebbink

Dept of Chemistry

extern

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Silicatein protein filaments isolated from marine demosponges have been used to influence the condensation of siloxanes bearing organometallic pincer complexes. The siliceous material is formed under remarkably mild conditions and the organometallic pincer becomes an intrinsic part of the silica. The immobilisation of a metal pincer, which acts as a sensor and initial results on the immobilisation of a pre-catalytic pincer species are reported

Original language	Undefined/Unknown
Pages (from-to)	4289-4291
Number of pages	3
Journal	Dalton Transactions
Volume	22
Publication status	Published - 2009

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 14 Life Below Water

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title = "Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments",

abstract = "Silicatein protein filaments isolated from marine demosponges have been used to influence the condensation of siloxanes bearing organometallic pincer complexes. The siliceous material is formed under remarkably mild conditions and the organometallic pincer becomes an intrinsic part of the silica. The immobilisation of a metal pincer, which acts as a sensor and initial results on the immobilisation of a pre-catalytic pincer species are reported",

author = "Patrick O'Leary and \{van Walree\}, C.A. and N.C. Mehendale and J. Summerel and D.E. Morse and \{van Koten\}, G. and \{Klein Gebbink\}, R.J.M.",

year = "2009",

language = "Undefined/Unknown",

volume = "22",

pages = "4289--4291",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments

AU - O'Leary, Patrick

AU - van Walree, C.A.

AU - Mehendale, N.C.

AU - Summerel, J.

AU - Morse, D.E.

AU - van Koten, G.

AU - Klein Gebbink, R.J.M.

PY - 2009

Y1 - 2009

N2 - Silicatein protein filaments isolated from marine demosponges have been used to influence the condensation of siloxanes bearing organometallic pincer complexes. The siliceous material is formed under remarkably mild conditions and the organometallic pincer becomes an intrinsic part of the silica. The immobilisation of a metal pincer, which acts as a sensor and initial results on the immobilisation of a pre-catalytic pincer species are reported

AB - Silicatein protein filaments isolated from marine demosponges have been used to influence the condensation of siloxanes bearing organometallic pincer complexes. The siliceous material is formed under remarkably mild conditions and the organometallic pincer becomes an intrinsic part of the silica. The immobilisation of a metal pincer, which acts as a sensor and initial results on the immobilisation of a pre-catalytic pincer species are reported

M3 - Article

SN - 1477-9226

VL - 22

SP - 4289

EP - 4291

JO - Dalton Transactions

JF - Dalton Transactions

ER -