Electrochemical kinetics of hydrogen intercalation in gadolinium switchable mirrors

M Di Vece; A.N. Swart; JJ Kelly; Ingmar Swart

doi:10.1063/1.1606863

Electrochemical kinetics of hydrogen intercalation in gadolinium switchable mirrors

M Di Vece^*, A.N. Swart, JJ Kelly, Ingmar Swart

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Potential-step experiments on gadolinium thin-film electrodes provide current and optical transmission transients, whose time constants are related to effective hydrogen diffusion coefficients according to a standard diffusion model. The diffusion coefficients and switching kinetics depend on temperature, hydrogen concentration, potential, and film thickness. A thickness dependence of the kinetics is observed in which the diffusion coefficient and optical switching time are linearly dependent. (C) 2003 American Institute of Physics.

Original language	English
Pages (from-to)	4659-4664
Number of pages	6
Journal	Journal of Applied Physics
Volume	94
Issue number	7
DOIs	https://doi.org/10.1063/1.1606863
Publication status	Published - 1 Oct 2003

Keywords

MODEL-INDEPENDENT MEASUREMENTS
OPTICAL-TRANSMISSION
HYDRIDE FILMS
DIFFUSION
YTTRIUM
SPECTROSCOPY
GD

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10.1063/1.1606863

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title = "Electrochemical kinetics of hydrogen intercalation in gadolinium switchable mirrors",

abstract = "Potential-step experiments on gadolinium thin-film electrodes provide current and optical transmission transients, whose time constants are related to effective hydrogen diffusion coefficients according to a standard diffusion model. The diffusion coefficients and switching kinetics depend on temperature, hydrogen concentration, potential, and film thickness. A thickness dependence of the kinetics is observed in which the diffusion coefficient and optical switching time are linearly dependent. (C) 2003 American Institute of Physics.",

keywords = "MODEL-INDEPENDENT MEASUREMENTS, OPTICAL-TRANSMISSION, HYDRIDE FILMS, DIFFUSION, YTTRIUM, SPECTROSCOPY, GD",

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T1 - Electrochemical kinetics of hydrogen intercalation in gadolinium switchable mirrors

AU - Di Vece, M

AU - Swart, A.N.

AU - Kelly, JJ

AU - Swart, Ingmar

PY - 2003/10/1

Y1 - 2003/10/1

N2 - Potential-step experiments on gadolinium thin-film electrodes provide current and optical transmission transients, whose time constants are related to effective hydrogen diffusion coefficients according to a standard diffusion model. The diffusion coefficients and switching kinetics depend on temperature, hydrogen concentration, potential, and film thickness. A thickness dependence of the kinetics is observed in which the diffusion coefficient and optical switching time are linearly dependent. (C) 2003 American Institute of Physics.

AB - Potential-step experiments on gadolinium thin-film electrodes provide current and optical transmission transients, whose time constants are related to effective hydrogen diffusion coefficients according to a standard diffusion model. The diffusion coefficients and switching kinetics depend on temperature, hydrogen concentration, potential, and film thickness. A thickness dependence of the kinetics is observed in which the diffusion coefficient and optical switching time are linearly dependent. (C) 2003 American Institute of Physics.

KW - MODEL-INDEPENDENT MEASUREMENTS

KW - OPTICAL-TRANSMISSION

KW - HYDRIDE FILMS

KW - DIFFUSION

KW - YTTRIUM

KW - SPECTROSCOPY

KW - GD

U2 - 10.1063/1.1606863

DO - 10.1063/1.1606863

M3 - Article

SN - 0021-8979

VL - 94

SP - 4659

EP - 4664

JO - Journal of Applied Physics

JF - Journal of Applied Physics

IS - 7

ER -

Electrochemical kinetics of hydrogen intercalation in gadolinium switchable mirrors

Abstract

Keywords

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