Direct evidence on the existence of [Mo132] Keplerate-type species in aqueous solution

S. Roy; K.L. Planken; R. Kim; D. van der Mandele; W.K. Kegel

Direct evidence on the existence of [Mo132] Keplerate-type species in aqueous solution

S. Roy, K.L. Planken, R. Kim, D. van der Mandele, W.K. Kegel

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

We demonstrate the existence of discrete single molecular [Mo132] Keplerate-type clusters in aqueous solution. Starting from a discrete spherical [Mo132] cluster, the formation of an open-basket-type [Mo116] defect structure is shown for the first time in solution using analytical ultracentrifugation sedimentation velocity experiments.

Original language	Undefined/Unknown
Pages (from-to)	8469-8471
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Publication status	Published - 2007

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Cite this

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title = "Direct evidence on the existence of [Mo132] Keplerate-type species in aqueous solution",

abstract = "We demonstrate the existence of discrete single molecular [Mo132] Keplerate-type clusters in aqueous solution. Starting from a discrete spherical [Mo132] cluster, the formation of an open-basket-type [Mo116] defect structure is shown for the first time in solution using analytical ultracentrifugation sedimentation velocity experiments.",

author = "S. Roy and K.L. Planken and R. Kim and {van der Mandele}, D. and W.K. Kegel",

year = "2007",

language = "Undefined/Unknown",

volume = "46",

pages = "8469--8471",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - Direct evidence on the existence of [Mo132] Keplerate-type species in aqueous solution

AU - Roy, S.

AU - Planken, K.L.

AU - Kim, R.

AU - van der Mandele, D.

AU - Kegel, W.K.

PY - 2007

Y1 - 2007

N2 - We demonstrate the existence of discrete single molecular [Mo132] Keplerate-type clusters in aqueous solution. Starting from a discrete spherical [Mo132] cluster, the formation of an open-basket-type [Mo116] defect structure is shown for the first time in solution using analytical ultracentrifugation sedimentation velocity experiments.

AB - We demonstrate the existence of discrete single molecular [Mo132] Keplerate-type clusters in aqueous solution. Starting from a discrete spherical [Mo132] cluster, the formation of an open-basket-type [Mo116] defect structure is shown for the first time in solution using analytical ultracentrifugation sedimentation velocity experiments.

M3 - Article

SN - 0020-1669

VL - 46

SP - 8469

EP - 8471

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -