Development of a 1H NMR structural-reporter-group concept for the primary structural characterisation of α-D-glucans

S.S. van Leeuwen; B.R. Leeflang; G.J. Gerwig; J.P. Kamerling

doi:10.1016/j.carres.2008.01.043

Development of a 1H NMR structural-reporter-group concept for the primary structural characterisation of α-D-glucans

S.S. van Leeuwen, B.R. Leeflang, G.J. Gerwig, J.P. Kamerling

Dep Scheikunde

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

An NMR study of proton chemical shift patterns of known linear α-d-glucopyranose di- and trisaccharide structures was carried out. Chemical shift patterns for (α1→2)-, (α1→3)-, (α1→4)- and (α1→6)-linked d-glucose residues were analysed and compared to literature data. Using these data, a 1H NMR structural-reporter-group concept was formulated to function as a tool in the structural analysis of α-d-glucans.

Original language	English
Pages (from-to)	1114-1119
Number of pages	7
Journal	Carbohydrate Research
Volume	343
Issue number	6
DOIs	https://doi.org/10.1016/j.carres.2008.01.043
Publication status	Published - 5 May 2008

Keywords

Structural-reporter-group concept
a-d-Glucan1
H NMR spectroscopy
Polysaccharide structural analysis

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10.1016/j.carres.2008.01.043

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title = "Development of a 1H NMR structural-reporter-group concept for the primary structural characterisation of α-D-glucans",

abstract = "An NMR study of proton chemical shift patterns of known linear α-d-glucopyranose di- and trisaccharide structures was carried out. Chemical shift patterns for (α1→2)-, (α1→3)-, (α1→4)- and (α1→6)-linked d-glucose residues were analysed and compared to literature data. Using these data, a 1H NMR structural-reporter-group concept was formulated to function as a tool in the structural analysis of α-d-glucans.",

keywords = "Structural-reporter-group concept, a-d-Glucan1, H NMR spectroscopy, Polysaccharide structural analysis",

author = "{van Leeuwen}, S.S. and B.R. Leeflang and G.J. Gerwig and J.P. Kamerling",

year = "2008",

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T1 - Development of a 1H NMR structural-reporter-group concept for the primary structural characterisation of α-D-glucans

AU - van Leeuwen, S.S.

AU - Leeflang, B.R.

AU - Gerwig, G.J.

AU - Kamerling, J.P.

PY - 2008/5/5

Y1 - 2008/5/5

N2 - An NMR study of proton chemical shift patterns of known linear α-d-glucopyranose di- and trisaccharide structures was carried out. Chemical shift patterns for (α1→2)-, (α1→3)-, (α1→4)- and (α1→6)-linked d-glucose residues were analysed and compared to literature data. Using these data, a 1H NMR structural-reporter-group concept was formulated to function as a tool in the structural analysis of α-d-glucans.

AB - An NMR study of proton chemical shift patterns of known linear α-d-glucopyranose di- and trisaccharide structures was carried out. Chemical shift patterns for (α1→2)-, (α1→3)-, (α1→4)- and (α1→6)-linked d-glucose residues were analysed and compared to literature data. Using these data, a 1H NMR structural-reporter-group concept was formulated to function as a tool in the structural analysis of α-d-glucans.

KW - Structural-reporter-group concept

KW - a-d-Glucan1

KW - H NMR spectroscopy

KW - Polysaccharide structural analysis

U2 - 10.1016/j.carres.2008.01.043

DO - 10.1016/j.carres.2008.01.043

M3 - Article

SN - 0008-6215

VL - 343

SP - 1114

EP - 1119

JO - Carbohydrate Research

JF - Carbohydrate Research

IS - 6

ER -

Development of a 1H NMR structural-reporter-group concept for the primary structural characterisation of α-D-glucans

Abstract

Keywords

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