Determination of the degree of aggregation of organocopper compounds by cryoscopy in tetrahydrofuran

A. Gerold; J. T B H Jastrzebski; C. M P Kronenburg; N. Krause; G. Van Koten

Determination of the degree of aggregation of organocopper compounds by cryoscopy in tetrahydrofuran

A. Gerold
, J. T B H Jastrzebski
, C. M P Kronenburg
, N. Krause^*
, G. Van Koten

^*Corresponding author for this work

IOCBU

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Organocuprates are mostly monomeric in solution! This is the result of the investigation of the aggregation behavior of reagents with the stoichiometry [R₂Cu(X)Li₂], carried out for the first time by cryoscopy in tetrahydrofuran. Thus, Gilman cuprates (X = I) and cyanocuprates (X = CN) may belong to the same structural type 1.

Original language	English
Pages (from-to)	755-757
Number of pages	3
Journal	Angewandte Chemie: International Edition
Volume	36
Issue number	7
Publication status	Published - 1997
Externally published	Yes

Keywords

Aggregation
Copper
Cryoscopy
Lithium

Cite this

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title = "Determination of the degree of aggregation of organocopper compounds by cryoscopy in tetrahydrofuran",

abstract = "Organocuprates are mostly monomeric in solution! This is the result of the investigation of the aggregation behavior of reagents with the stoichiometry [R2Cu(X)Li2], carried out for the first time by cryoscopy in tetrahydrofuran. Thus, Gilman cuprates (X = I) and cyanocuprates (X = CN) may belong to the same structural type 1.",

keywords = "Aggregation, Copper, Cryoscopy, Lithium",

author = "A. Gerold and Jastrzebski, \{J. T B H\} and Kronenburg, \{C. M P\} and N. Krause and \{Van Koten\}, G.",

year = "1997",

language = "English",

volume = "36",

pages = "755--757",

journal = "Angewandte Chemie: International Edition",

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T1 - Determination of the degree of aggregation of organocopper compounds by cryoscopy in tetrahydrofuran

AU - Gerold, A.

AU - Jastrzebski, J. T B H

AU - Kronenburg, C. M P

AU - Krause, N.

AU - Van Koten, G.

PY - 1997

Y1 - 1997

N2 - Organocuprates are mostly monomeric in solution! This is the result of the investigation of the aggregation behavior of reagents with the stoichiometry [R2Cu(X)Li2], carried out for the first time by cryoscopy in tetrahydrofuran. Thus, Gilman cuprates (X = I) and cyanocuprates (X = CN) may belong to the same structural type 1.

AB - Organocuprates are mostly monomeric in solution! This is the result of the investigation of the aggregation behavior of reagents with the stoichiometry [R2Cu(X)Li2], carried out for the first time by cryoscopy in tetrahydrofuran. Thus, Gilman cuprates (X = I) and cyanocuprates (X = CN) may belong to the same structural type 1.

KW - Aggregation

KW - Copper

KW - Cryoscopy

KW - Lithium

UR - https://www.scopus.com/pages/publications/0030818860

M3 - Article

AN - SCOPUS:0030818860

SN - 0570-0833

VL - 36

SP - 755

EP - 757

JO - Angewandte Chemie: International Edition

JF - Angewandte Chemie: International Edition

IS - 7

ER -

Determination of the degree of aggregation of organocopper compounds by cryoscopy in tetrahydrofuran

Abstract

Keywords

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