Detection of scalar 6Li,15N coupling across coordinative Li-N bonds

D. Huls; H. Gunther; G. Van Koten; P. Wijkens; J. T B H Jastrzebski

Detection of scalar 6Li,15N coupling across coordinative Li-N bonds

D. Huls, H. Gunther^*, G. Van Koten, P. Wijkens, J. T B H Jastrzebski

^*Corresponding author for this work

Fachbereich 8 der Universitat

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

With natural abundance of ¹⁵N in the sample, scalar ⁶Li, ¹⁵N spin- spin couplings across coordinative Li-N bonds were detected for the tetrameric organolithium compound 1 in solution and in the solid state. The coupling constants of 3.6 and 4.2 Hz correlate with the Li-N distances determined in the crystal structure analysis.

Original language	English
Pages (from-to)	2629-2631
Number of pages	3
Journal	Angewandte Chemie: International Edition
Volume	36
Issue number	23
Publication status	Published - 15 Dec 1997
Externally published	Yes

Keywords

Ligand effects
Lithium
NMR spectroscopy

Cite this

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title = "Detection of scalar 6Li,15N coupling across coordinative Li-N bonds",

abstract = "With natural abundance of 15N in the sample, scalar 6Li, 15N spin- spin couplings across coordinative Li-N bonds were detected for the tetrameric organolithium compound 1 in solution and in the solid state. The coupling constants of 3.6 and 4.2 Hz correlate with the Li-N distances determined in the crystal structure analysis.",

keywords = "Ligand effects, Lithium, NMR spectroscopy",

author = "D. Huls and H. Gunther and {Van Koten}, G. and P. Wijkens and Jastrzebski, {J. T B H}",

year = "1997",

month = dec,

day = "15",

language = "English",

volume = "36",

pages = "2629--2631",

journal = "Angewandte Chemie: International Edition",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

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TY - JOUR

T1 - Detection of scalar 6Li,15N coupling across coordinative Li-N bonds

AU - Huls, D.

AU - Gunther, H.

AU - Van Koten, G.

AU - Wijkens, P.

AU - Jastrzebski, J. T B H

PY - 1997/12/15

Y1 - 1997/12/15

N2 - With natural abundance of 15N in the sample, scalar 6Li, 15N spin- spin couplings across coordinative Li-N bonds were detected for the tetrameric organolithium compound 1 in solution and in the solid state. The coupling constants of 3.6 and 4.2 Hz correlate with the Li-N distances determined in the crystal structure analysis.

AB - With natural abundance of 15N in the sample, scalar 6Li, 15N spin- spin couplings across coordinative Li-N bonds were detected for the tetrameric organolithium compound 1 in solution and in the solid state. The coupling constants of 3.6 and 4.2 Hz correlate with the Li-N distances determined in the crystal structure analysis.

KW - Ligand effects

KW - Lithium

KW - NMR spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=0031573814&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0031573814

SN - 0570-0833

VL - 36

SP - 2629

EP - 2631

JO - Angewandte Chemie: International Edition

JF - Angewandte Chemie: International Edition

IS - 23

ER -

Detection of scalar 6Li,15N coupling across coordinative Li-N bonds

Abstract

Keywords

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