Cyclometallation of Aryl-Substituted Phosphinines through C-H-Bond Activation: A Mechanistic Investigation

Keyphrases

• Phosphinines 100%
• C-H Bond Activation 100%
• Aryl 100%
• Mechanistic Investigation 100%
• Cyclometallation 100%
• Phosphorus 50%
• Metal Center 50%
• NMR Spectroscopy 50%
• Metal Precursor 50%
• Room Temperature 50%
• Ortho 50%
• C-H Bond 50%
• Activation Energy 50%
• Regioselectivity 50%
• Steric Effect 50%
• Acetate 50%
• Cyclometalated 50%
• Activation Mechanism 50%
• CP-1 50%
• Decamethylcyclopentasiloxane 50%
• 1H NMR Spectroscopy 50%
• H Activation 50%
• Crystal X-ray Diffraction 50%
• Observed Trends 50%
• Dissociation Step 50%

Chemistry

• Single Crystal X-Ray Diffraction 100%
• Ambient Reaction Temperature 100%
• Reaction Activation Energy 100%
• Steric Effect 100%
• Regioselectivity 100%
• C-H Bond Activation 100%
• 31P{1H}-NMR Spectroscopy 100%
• Base 100%
• Phosphorus 100%
• dimer 100%