TY - JOUR
T1 - Cover Feature: Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton‐Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C−H Bond in H 2 Formation (Chem. Eur. J. 55/2020)
AU - Ghosh, Pradip
AU - Vos, Sander
AU - Lutz, Martin
AU - Gloaguen, Frederic
AU - Schollhammer, Philippe
AU - Moret, Marc‐Etienne
AU - Klein Gebbink, Robertus J. M.
PY - 2020/10/1
Y1 - 2020/10/1
N2 - The design of proton‐responsive ligands and their use in the field of homogeneous electrocatalytic proton reduction is reported in this work. The cobalt complex, [Co(HBMIMPh2)2]2+ comprises two bis(1‐methyl‐4,5‐diphenyl‐1H‐imidazol‐2‐yl)methane (HBMIMPh2) ligands that contain an acidic methylene moiety in their backbone. The reported results represent the joint involvement of a base metal‐hydride and a C−H bond in electrocatalytic proton reduction and are of interest to the development of responsive ligands for molecular (base)metal (electro)catalysis. More information can be found in the Full Paper by R. J. M. Klein Gebbink et al. on page 12560.
AB - The design of proton‐responsive ligands and their use in the field of homogeneous electrocatalytic proton reduction is reported in this work. The cobalt complex, [Co(HBMIMPh2)2]2+ comprises two bis(1‐methyl‐4,5‐diphenyl‐1H‐imidazol‐2‐yl)methane (HBMIMPh2) ligands that contain an acidic methylene moiety in their backbone. The reported results represent the joint involvement of a base metal‐hydride and a C−H bond in electrocatalytic proton reduction and are of interest to the development of responsive ligands for molecular (base)metal (electro)catalysis. More information can be found in the Full Paper by R. J. M. Klein Gebbink et al. on page 12560.
UR - https://www.mendeley.com/catalogue/b5d829d8-d931-35eb-966e-0a195b5ecd83/
U2 - 10.1002/chem.202003332
DO - 10.1002/chem.202003332
M3 - Article
SN - 0947-6539
VL - 26
SP - 12490
EP - 12490
JO - Chemistry-A European Journal
JF - Chemistry-A European Journal
IS - 55
ER -