Coulometry and Calorimetry of Electric Double Layer Formation in Porous Electrodes

Mathijs Janssen*, Elian Griffioen, P. M. Biesheuvel, René Van Roij, Ben Erné

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

Coulometric measurements on salt-water-immersed nanoporous carbon electrodes reveal, at a fixed voltage, a charge decrease with increasing temperature. During far-out-of-equilibrium charging of these electrodes, calorimetry indicates the production of both irreversible Joule heat and reversible heat, the latter being associated with entropy changes during electric double layer (EDL) formation in the nanopores. These measurements grant experimental access - for the first time - to the entropic contribution of the grand potential; for our electrodes, this amounts to roughly 25% of the total grand potential energy cost of EDL formation at large applied potentials, in contrast with point-charge model calculations that predict 100%. The coulometric and calorimetric experiments show a consistent picture of the role of heat and temperature in EDL formation and provide hitherto unused information to test against EDL models.

Original languageEnglish
Article number166002
Number of pages5
JournalPhysical Review Letters
Volume119
Issue number16
DOIs
Publication statusPublished - 19 Oct 2017

Keywords

  • Capacitance
  • Electric double layers
  • Electrochemistry
  • Nonequilibrium & irreversible thermodynamics
  • Thermodynamics
  • Thermodynamics of mixing

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