Copper sulfide derived nanoparticles supported on carbon for the electrochemical reduction of carbon dioxide

Christina H.M. van Oversteeg, Marisol Tapia Rosales, Kristiaan H. Helfferich, Mahnaz Ghiasi, Johannes D. Meeldijk, Nienke J. Firet, Peter Ngene, Celso de Mello Donegá, Petra E. de Jongh*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review


The electrocatalytic reduction of CO2 to produce sustainable fuels and chemicals is attracting great attention. Cu-based catalysts can lead to the production of a range of different molecules, and interestingly the product selectivity strongly depends on the preparation history, although it is not fully understood yet why. We report a novel strategy that allowed us to prepare Cu nanoparticle on carbon catalysts with similar morphologies, but prepared by in-situ reduction of either supported CuS, Cu2S or CuO nanoparticles. For the first time the evolution of the Cu species was followed under CO2 and H+ reduction conditions using in-situ X-ray absorption spectroscopy. Excellent electrochemical contact between the Cu-based nanoparticles, the carbon support and the carbon-paper substrate was observed, resulting in metallic Cu as the predominant phase under typical electrochemical CO2 reduction conditions. Even covering less than 4% of the H2 producing carbon support with Cu-sulfide derived nanoparticles allowed to steer the selectivity to a maximum of 12% Faradaic efficiency for the production of formate. Clear differences between the catalysts derived from CuS, Cu2S or CuO nanoparticles were observed, which was ascribed to the presence of residual sulfur in the catalysts.

Original languageEnglish
Pages (from-to)157-165
Number of pages9
JournalCatalysis Today
Early online date1 Oct 2020
Publication statusPublished - 1 Oct 2021


  • Carbon support
  • CO reduction
  • Copper sulfide
  • In situ X-ray absorption spectroscopy
  • Nanoparticles
  • Sulfidation


Dive into the research topics of 'Copper sulfide derived nanoparticles supported on carbon for the electrochemical reduction of carbon dioxide'. Together they form a unique fingerprint.

Cite this