Convergent functional groups XIV. Synthesis and binding studies of new molecular clefts for recognition and catalysis

Roland J. Pieters; Julius Rebek

doi:10.1002/recl.19931120604

Convergent functional groups XIV. Synthesis and binding studies of new molecular clefts for recognition and catalysis

Roland J. Pieters^*
, Julius Rebek

^*Corresponding author for this work

Massachusetts Institute of Technology
extern

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Two new molecular clefts have been synthesized, both containing an adenine receptor portion and a metal‐binding site. The binding of adenine derivatives was evaluated in CDCl₃, acetone‐d₆ and water using NMR titrations. Base‐paired hydrogen‐bonded complexes are formed in all three solvents, but structural differences in the complexes are also observed. The Cu^II binding ability was established using UV spectroscopy.

Original language	English
Pages (from-to)	330-334
Number of pages	5
Journal	Recueil des Travaux Chimiques des Pays‐Bas
Volume	112
Issue number	6
DOIs	https://doi.org/10.1002/recl.19931120604
Publication status	Published - 1993
Externally published	Yes

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title = "Convergent functional groups XIV. Synthesis and binding studies of new molecular clefts for recognition and catalysis",

abstract = "Two new molecular clefts have been synthesized, both containing an adenine receptor portion and a metal‐binding site. The binding of adenine derivatives was evaluated in CDCl3, acetone‐d6 and water using NMR titrations. Base‐paired hydrogen‐bonded complexes are formed in all three solvents, but structural differences in the complexes are also observed. The CuII binding ability was established using UV spectroscopy.",

author = "Pieters, \{Roland J.\} and Julius Rebek",

year = "1993",

doi = "10.1002/recl.19931120604",

language = "English",

volume = "112",

pages = "330--334",

journal = "Recueil des Travaux Chimiques des Pays‐Bas",

issn = "0165-0513",

publisher = "Koninklijke Nederlandse Chemische Vereniging",

number = "6",

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TY - JOUR

T1 - Convergent functional groups XIV. Synthesis and binding studies of new molecular clefts for recognition and catalysis

AU - Pieters, Roland J.

AU - Rebek, Julius

PY - 1993

Y1 - 1993

N2 - Two new molecular clefts have been synthesized, both containing an adenine receptor portion and a metal‐binding site. The binding of adenine derivatives was evaluated in CDCl3, acetone‐d6 and water using NMR titrations. Base‐paired hydrogen‐bonded complexes are formed in all three solvents, but structural differences in the complexes are also observed. The CuII binding ability was established using UV spectroscopy.

AB - Two new molecular clefts have been synthesized, both containing an adenine receptor portion and a metal‐binding site. The binding of adenine derivatives was evaluated in CDCl3, acetone‐d6 and water using NMR titrations. Base‐paired hydrogen‐bonded complexes are formed in all three solvents, but structural differences in the complexes are also observed. The CuII binding ability was established using UV spectroscopy.

UR - https://www.scopus.com/pages/publications/0012015955

U2 - 10.1002/recl.19931120604

DO - 10.1002/recl.19931120604

M3 - Article

AN - SCOPUS:0012015955

SN - 0165-0513

VL - 112

SP - 330

EP - 334

JO - Recueil des Travaux Chimiques des Pays‐Bas

JF - Recueil des Travaux Chimiques des Pays‐Bas

IS - 6

ER -

Convergent functional groups XIV. Synthesis and binding studies of new molecular clefts for recognition and catalysis

Abstract

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