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Control of structure formation in phase-separating systems

  • A. Singh
  • , A. Mukherjee
  • , H.M. Vermeulen
  • , G.T. Barkema
  • , S. Puri
  • extern

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

In this paper, we study the evolution of phase-separating binary mixtures which are subjected to alternate cooling and heating cycles. An initially homogeneous mixture is rapidly quenched to a temperature T1 <Tc, where Tc is the critical temperature. The mixture undergoes phase separation for a while and is then suddenly heated to a temperature T2 > Tc. These cycles are repeated to create a domain morphology with multiple length scales, i.e., the structure factor is characterized by multiple peaks. For phase separation in d = 2 systems, we present numerical and analytical results for the emergence and growth of this multiple-scale morphology.
Original languageEnglish
Number of pages8
JournalJournal of Chemical Physics
Volume134
Issue number044910
DOIs
Publication statusPublished - 2011

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