Concentration enhancement of the vibronic transitions of the Pr3+ ion

C. de Mello Donegá; A. Ellens; A. Meijerink; G. Blasse

doi:10.1016/0022-3697(93)90261-O

Concentration enhancement of the vibronic transitions of the Pr3+ ion

C. de Mello Donegá, A. Ellens, A. Meijerink, G. Blasse

Sub Condensed Matter and Interfaces

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The effects of the Pr3+ concentration on the excitation and emission spectra of Pr3+ in (La1−xPrx)2O3, (RE1−x)Prx2O2S (RE = Y, La) (x ⩽0.2), and LiY1−xPrxF4(x⩽0.1) are investigated. Concentration enhancement of vibronic transitions and of certain zero-phonon transitions is observed for the excitation spectrum of Pr3+ in (La1−xPrx)2O3 and (RE1−xPrx)2O2S. These phenomena can be ascribed to superexchange interaction between Pr3+ ions over distances of about 10 Å.

Original language	English
Pages (from-to)	293-300
Journal	Journal of Physics and Chemistry of Solids
Volume	54
Issue number	3
DOIs	https://doi.org/10.1016/0022-3697(93)90261-O
Publication status	Published - 1993

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10.1016/0022-3697(93)90261-O

http://adsabs.harvard.edu/abs/1993JPCS...54..293D

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title = "Concentration enhancement of the vibronic transitions of the Pr3+ ion",

abstract = "The effects of the Pr3+ concentration on the excitation and emission spectra of Pr3+ in (La1−xPrx)2O3, (RE1−x)Prx2O2S (RE = Y, La) (x ⩽0.2), and LiY1−xPrxF4(x⩽0.1) are investigated. Concentration enhancement of vibronic transitions and of certain zero-phonon transitions is observed for the excitation spectrum of Pr3+ in (La1−xPrx)2O3 and (RE1−xPrx)2O2S. These phenomena can be ascribed to superexchange interaction between Pr3+ ions over distances of about 10 {\AA}.",

author = "{de Mello Doneg{\'a}}, C. and A. Ellens and A. Meijerink and G. Blasse",

year = "1993",

doi = "10.1016/0022-3697(93)90261-O",

language = "English",

volume = "54",

pages = "293--300",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier Ltd",

number = "3",

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TY - JOUR

T1 - Concentration enhancement of the vibronic transitions of the Pr3+ ion

AU - de Mello Donegá, C.

AU - Ellens, A.

AU - Meijerink, A.

AU - Blasse, G.

PY - 1993

Y1 - 1993

N2 - The effects of the Pr3+ concentration on the excitation and emission spectra of Pr3+ in (La1−xPrx)2O3, (RE1−x)Prx2O2S (RE = Y, La) (x ⩽0.2), and LiY1−xPrxF4(x⩽0.1) are investigated. Concentration enhancement of vibronic transitions and of certain zero-phonon transitions is observed for the excitation spectrum of Pr3+ in (La1−xPrx)2O3 and (RE1−xPrx)2O2S. These phenomena can be ascribed to superexchange interaction between Pr3+ ions over distances of about 10 Å.

AB - The effects of the Pr3+ concentration on the excitation and emission spectra of Pr3+ in (La1−xPrx)2O3, (RE1−x)Prx2O2S (RE = Y, La) (x ⩽0.2), and LiY1−xPrxF4(x⩽0.1) are investigated. Concentration enhancement of vibronic transitions and of certain zero-phonon transitions is observed for the excitation spectrum of Pr3+ in (La1−xPrx)2O3 and (RE1−xPrx)2O2S. These phenomena can be ascribed to superexchange interaction between Pr3+ ions over distances of about 10 Å.

U2 - 10.1016/0022-3697(93)90261-O

DO - 10.1016/0022-3697(93)90261-O

M3 - Article

SN - 0022-3697

VL - 54

SP - 293

EP - 300

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

IS - 3

ER -

Concentration enhancement of the vibronic transitions of the Pr3+ ion

Abstract

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