Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions

Dide G. A. Verhoeven; Joost Kwakernaak; Maxime A. C. Van Wiggen; Martin Lutz; Marc-Etienne Moret

doi:10.1002/ejic.201801221

Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions

Dide G. A. Verhoeven
, Joost Kwakernaak
, Maxime A. C. Van Wiggen
, Martin Lutz
, Marc-Etienne Moret

Sub Organic Chemistry and Catalysis

Utrecht University

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The catalytic activity of cobalt(II) and cobalt(I) complexes of the diphosphine ketone ligand pToldpbp is demonstrated in the hydrosilylation of 1‐octene with phenylsilane under mild conditions, showing the first catalytic application of dpbp ligands in combination with base metals.

Original language	English
Pages (from-to)	660-667
Journal	European Journal of Inorganic Chemistry
Volume	2019
Issue number	5
DOIs	https://doi.org/10.1002/ejic.201801221
Publication status	Published - 7 Feb 2019

Keywords

Silane chemistry
Cobalt
Hydrosilylation
Homogeneous catalysis
Cooperative catalysis

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Verhoeven_et_al-2019-European_Journal_of_Inorganic_ChemistryFinal published version, 1.04 MB

http://doi.wiley.com/10.1002/ejic.201801221

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title = "Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions",

abstract = "The catalytic activity of cobalt(II) and cobalt(I) complexes of the diphosphine ketone ligand pToldpbp is demonstrated in the hydrosilylation of 1‐octene with phenylsilane under mild conditions, showing the first catalytic application of dpbp ligands in combination with base metals.",

keywords = "Silane chemistry, Cobalt, Hydrosilylation, Homogeneous catalysis, Cooperative catalysis",

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T1 - Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions

AU - Verhoeven, Dide G. A.

AU - Kwakernaak, Joost

AU - Van Wiggen, Maxime A. C.

AU - Lutz, Martin

AU - Moret, Marc-Etienne

PY - 2019/2/7

Y1 - 2019/2/7

N2 - The catalytic activity of cobalt(II) and cobalt(I) complexes of the diphosphine ketone ligand pToldpbp is demonstrated in the hydrosilylation of 1‐octene with phenylsilane under mild conditions, showing the first catalytic application of dpbp ligands in combination with base metals.

AB - The catalytic activity of cobalt(II) and cobalt(I) complexes of the diphosphine ketone ligand pToldpbp is demonstrated in the hydrosilylation of 1‐octene with phenylsilane under mild conditions, showing the first catalytic application of dpbp ligands in combination with base metals.

KW - Silane chemistry

KW - Cobalt

KW - Hydrosilylation

KW - Homogeneous catalysis

KW - Cooperative catalysis

U2 - 10.1002/ejic.201801221

DO - 10.1002/ejic.201801221

M3 - Article

SN - 1434-1948

VL - 2019

SP - 660

EP - 667

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 5

ER -

Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions

Abstract

Keywords

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