Clickable Mesoporous Silica via Functionalization with 1,ω-Alkenes

Sebastiaan A. Van Den Berg; Jing Tu; Karen M. Sliedregt; Alexander Kros; Tom Wennekes; Han Zuilhof

doi:10.1002/admi.201300061

Clickable Mesoporous Silica via Functionalization with 1,ω-Alkenes

Sebastiaan A. Van Den Berg, Jing Tu, Karen M. Sliedregt, Alexander Kros, Tom Wennekes^*, Han Zuilhof

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Tuning the surface properties of mesoporous silica is desirable for many applications, such as catalysis. We present a new modification method of calcined mesoporous silica, based on the thermal grafting of 1,7-octadiene. This easy method generates a high loading of terminal alkenes. We show that the modified surface is directly available for thiol-ene click chemistry, which enables a wide variety of molecules to be attached to this alkene-functionalized mesoporous silica.

Original language	English
Article number	1300061
Journal	Advanced Materials Interfaces
Volume	1
Issue number	3
DOIs	https://doi.org/10.1002/admi.201300061
Publication status	Published - 1 Jun 2014
Externally published	Yes

Keywords

organic/inorganic interfaces
surface modification and engineering
surface reactions

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10.1002/admi.201300061

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title = "Clickable Mesoporous Silica via Functionalization with 1,ω-Alkenes",

abstract = "Tuning the surface properties of mesoporous silica is desirable for many applications, such as catalysis. We present a new modification method of calcined mesoporous silica, based on the thermal grafting of 1,7-octadiene. This easy method generates a high loading of terminal alkenes. We show that the modified surface is directly available for thiol-ene click chemistry, which enables a wide variety of molecules to be attached to this alkene-functionalized mesoporous silica.",

keywords = "organic/inorganic interfaces, surface modification and engineering, surface reactions",

author = "{Van Den Berg}, {Sebastiaan A.} and Jing Tu and Sliedregt, {Karen M.} and Alexander Kros and Tom Wennekes and Han Zuilhof",

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doi = "10.1002/admi.201300061",

language = "English",

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AU - Van Den Berg, Sebastiaan A.

AU - Tu, Jing

AU - Sliedregt, Karen M.

AU - Kros, Alexander

AU - Wennekes, Tom

AU - Zuilhof, Han

PY - 2014/6/1

Y1 - 2014/6/1

N2 - Tuning the surface properties of mesoporous silica is desirable for many applications, such as catalysis. We present a new modification method of calcined mesoporous silica, based on the thermal grafting of 1,7-octadiene. This easy method generates a high loading of terminal alkenes. We show that the modified surface is directly available for thiol-ene click chemistry, which enables a wide variety of molecules to be attached to this alkene-functionalized mesoporous silica.

AB - Tuning the surface properties of mesoporous silica is desirable for many applications, such as catalysis. We present a new modification method of calcined mesoporous silica, based on the thermal grafting of 1,7-octadiene. This easy method generates a high loading of terminal alkenes. We show that the modified surface is directly available for thiol-ene click chemistry, which enables a wide variety of molecules to be attached to this alkene-functionalized mesoporous silica.

KW - organic/inorganic interfaces

KW - surface modification and engineering

KW - surface reactions

UR - http://www.scopus.com/inward/record.url?scp=84942362181&partnerID=8YFLogxK

U2 - 10.1002/admi.201300061

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JO - Advanced Materials Interfaces

JF - Advanced Materials Interfaces

IS - 3

M1 - 1300061

ER -

Clickable Mesoporous Silica via Functionalization with 1,ω-Alkenes

Abstract

Keywords

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