Abstract
The Kbeta x-ray emission spectra of divalent nickel compounds are analysed with both the crystal field multiplet model and the charge transfer multiplet model. The spin-dependent Kbeta x-ray emission spectrum is calculated and it is shown that the charge transfer effect is rather different in nature for spin-up (2A2) and spin-down (4A2) symmetry states. In Case the of a spin-up symmetry state it is shown that multiplet-induced mixing strongly affects the spectral shape. It is argued that renormalized crystal field multiplet calculations remain a useful approach to describe the Kbeta x-ray emission spectral shape.
| Original language | English |
|---|---|
| Pages (from-to) | 6875-6884 |
| Number of pages | 10 |
| Journal | Journal of physics. Condensed matter |
| Volume | 6 |
| Issue number | 34 |
| Publication status | Published - 22 Aug 1994 |
| Externally published | Yes |
Keywords
- TRANSITION-METAL COMPOUNDS
- ABSORPTION
- SPECTROSCOPY
- HALIDES