C-H Activation of 2,4,6-Triphenylphosphinine: Synthesis and Characterization of the First Homoleptic Phosphinine-Iridium(III) Complex fac-[Ir(C^P)3]

L.E.E. Broeckx; W. Delaunay; C. Latouche; M. Lutz; A. Boucekkine; M. Hissler; Christian Müller

doi:10.1021/ic401933m

C-H Activation of 2,4,6-Triphenylphosphinine: Synthesis and Characterization of the First Homoleptic Phosphinine-Iridium(III) Complex fac-[Ir(C^P)3]

L.E.E. Broeckx, W. Delaunay, C. Latouche, M. Lutz, A. Boucekkine, M. Hissler, Christian Müller

Sub Crystal and Structural Chemistry

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Abstract

Access to homoleptic phosphinine-based coordination compounds of d6 metals has so far remained elusive. We report here on the preparation and full characterization of the first homoleptic phosphinine− iridium(III) complex, obtained by C−H activation of 2,4,6-triphenylphosphinine with [Ir(acac)3]. This result opens up new perspectives for the implementation of such aromatic heterocycles in more applied research fields.

Original language	English
Pages (from-to)	10738-10740
Number of pages	3
Journal	Inorganic Chemistry
Volume	52
Issue number	19
DOIs	https://doi.org/10.1021/ic401933m
Publication status	Published - 2013

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title = "C-H Activation of 2,4,6-Triphenylphosphinine: Synthesis and Characterization of the First Homoleptic Phosphinine-Iridium(III) Complex fac-[Ir(C^P)3]",

abstract = "Access to homoleptic phosphinine-based coordination compounds of d6 metals has so far remained elusive. We report here on the preparation and full characterization of the first homoleptic phosphinine− iridium(III) complex, obtained by C−H activation of 2,4,6-triphenylphosphinine with [Ir(acac)3]. This result opens up new perspectives for the implementation of such aromatic heterocycles in more applied research fields.",

author = "L.E.E. Broeckx and W. Delaunay and C. Latouche and M. Lutz and A. Boucekkine and M. Hissler and Christian M{\"u}ller",

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doi = "10.1021/ic401933m",

language = "English",

volume = "52",

pages = "10738--10740",

journal = "Inorganic Chemistry",

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T1 - C-H Activation of 2,4,6-Triphenylphosphinine: Synthesis and Characterization of the First Homoleptic Phosphinine-Iridium(III) Complex fac-[Ir(C^P)3]

AU - Broeckx, L.E.E.

AU - Delaunay, W.

AU - Latouche, C.

AU - Lutz, M.

AU - Boucekkine, A.

AU - Hissler, M.

AU - Müller, Christian

PY - 2013

Y1 - 2013

N2 - Access to homoleptic phosphinine-based coordination compounds of d6 metals has so far remained elusive. We report here on the preparation and full characterization of the first homoleptic phosphinine− iridium(III) complex, obtained by C−H activation of 2,4,6-triphenylphosphinine with [Ir(acac)3]. This result opens up new perspectives for the implementation of such aromatic heterocycles in more applied research fields.

AB - Access to homoleptic phosphinine-based coordination compounds of d6 metals has so far remained elusive. We report here on the preparation and full characterization of the first homoleptic phosphinine− iridium(III) complex, obtained by C−H activation of 2,4,6-triphenylphosphinine with [Ir(acac)3]. This result opens up new perspectives for the implementation of such aromatic heterocycles in more applied research fields.

U2 - 10.1021/ic401933m

DO - 10.1021/ic401933m

M3 - Article

SN - 0020-1669

VL - 52

SP - 10738

EP - 10740

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 19

ER -

C-H Activation of 2,4,6-Triphenylphosphinine: Synthesis and Characterization of the First Homoleptic Phosphinine-Iridium(III) Complex fac-[Ir(C^P)3]

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