Bis(acetato-κO)bis(thiourea-κS)cobalt(II)

Martin Lutz

doi:10.1107/S1600536814002074

Bis(acetato-κO)bis(thiourea-κS)cobalt(II)

Martin Lutz^*

^*Corresponding author for this work

Utrecht University

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The title compound, [Co(CH₃COO)₂ (CH ₄N₂S)₂], is isotypic with the corresponding Zn^II complex. The metal atom is in a distorted tetrahedral coordination environment with the two S atoms from two thiourea ligands and two O atoms from two acetate anions as the coordinating atoms. All H atoms of the thiourea ligands are involved in N - H⋯O and N - H⋯S hydrogen bonds, leading to a three-dimensional network.

Original language	English
Article number	m78
Number of pages	8
Journal	Acta crystallographica. Section E, Structure reports
Volume	70
Issue number	3
DOIs	https://doi.org/10.1107/S1600536814002074
Publication status	Published - 1 Mar 2014

Keywords

Data-to-parameter ratio = 16.2
Mean σ(C-C) = 0.002 Å
R factor = 0.016
Single-crystal X-ray study
T = 150 K
wR factor = 0.041

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title = "Bis(acetato-κO)bis(thiourea-κS)cobalt(II)",

abstract = "The title compound, [Co(CH3COO)2 (CH 4N2S)2], is isotypic with the corresponding ZnII complex. The metal atom is in a distorted tetrahedral coordination environment with the two S atoms from two thiourea ligands and two O atoms from two acetate anions as the coordinating atoms. All H atoms of the thiourea ligands are involved in N - H⋯O and N - H⋯S hydrogen bonds, leading to a three-dimensional network.",

keywords = "Data-to-parameter ratio = 16.2, Mean σ(C-C) = 0.002 {\AA}, R factor = 0.016, Single-crystal X-ray study, T = 150 K, wR factor = 0.041",

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year = "2014",

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doi = "10.1107/S1600536814002074",

language = "English",

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T1 - Bis(acetato-κO)bis(thiourea-κS)cobalt(II)

AU - Lutz, Martin

PY - 2014/3/1

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N2 - The title compound, [Co(CH3COO)2 (CH 4N2S)2], is isotypic with the corresponding ZnII complex. The metal atom is in a distorted tetrahedral coordination environment with the two S atoms from two thiourea ligands and two O atoms from two acetate anions as the coordinating atoms. All H atoms of the thiourea ligands are involved in N - H⋯O and N - H⋯S hydrogen bonds, leading to a three-dimensional network.

AB - The title compound, [Co(CH3COO)2 (CH 4N2S)2], is isotypic with the corresponding ZnII complex. The metal atom is in a distorted tetrahedral coordination environment with the two S atoms from two thiourea ligands and two O atoms from two acetate anions as the coordinating atoms. All H atoms of the thiourea ligands are involved in N - H⋯O and N - H⋯S hydrogen bonds, leading to a three-dimensional network.

KW - Data-to-parameter ratio = 16.2

KW - Mean σ(C-C) = 0.002 Å

KW - R factor = 0.016

KW - Single-crystal X-ray study

KW - T = 150 K

KW - wR factor = 0.041

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U2 - 10.1107/S1600536814002074

DO - 10.1107/S1600536814002074

M3 - Article

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SN - 1600-5368

VL - 70

JO - Acta crystallographica. Section E, Structure reports

JF - Acta crystallographica. Section E, Structure reports

IS - 3

M1 - m78

ER -

Bis(acetato-κO)bis(thiourea-κS)cobalt(II)

Abstract

Keywords

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