Bis{2-[(dimethylamino-κN)methyl]-benzenethiolato-κS}zinc(II)

L.S. von Chrzanowski; M. Lutz; A.L. Spek; H. Kleijn; G. van Koten

Bis{2-[(dimethylamino-κN)methyl]-benzenethiolato-κS}zinc(II)

L.S. von Chrzanowski, M. Lutz, A.L. Spek, H. Kleijn, G. van Koten

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

In the title compound, [Zn(C9H12NS)2], the ZnII center is located on a twofold rotation axis and is coordinated in a distorted tetrahedral environment in a bidentate fashion by anionic thiolate S and neutral amino N atoms of two 2-[(dimethylamino)methyl]benzenethiolate ligands. All the molecules are in the form. The chosen crystal can thus be considered enantiomerically pure. Intermolecular C-H...π contacts connect the molecules into a two-dimensional network.

Original language	Undefined/Unknown
Pages (from-to)	m1847
Number of pages	10
Journal	Acta crystallographica. Section E, Structure reports
Volume	63
Issue number	7
Publication status	Published - 2007

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Cite this

@article{f4f29620c7124325aab9848c0d90da1d,

title = "Bis{2-[(dimethylamino-κN)methyl]-benzenethiolato-κS}zinc(II)",

abstract = "In the title compound, [Zn(C9H12NS)2], the ZnII center is located on a twofold rotation axis and is coordinated in a distorted tetrahedral environment in a bidentate fashion by anionic thiolate S and neutral amino N atoms of two 2-[(dimethylamino)methyl]benzenethiolate ligands. All the molecules are in the form. The chosen crystal can thus be considered enantiomerically pure. Intermolecular C-H...π contacts connect the molecules into a two-dimensional network.",

author = "{von Chrzanowski}, L.S. and M. Lutz and A.L. Spek and H. Kleijn and {van Koten}, G.",

year = "2007",

language = "Undefined/Unknown",

volume = "63",

pages = "m1847",

journal = "Acta crystallographica. Section E, Structure reports",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - Bis{2-[(dimethylamino-κN)methyl]-benzenethiolato-κS}zinc(II)

AU - von Chrzanowski, L.S.

AU - Lutz, M.

AU - Spek, A.L.

AU - Kleijn, H.

AU - van Koten, G.

PY - 2007

Y1 - 2007

N2 - In the title compound, [Zn(C9H12NS)2], the ZnII center is located on a twofold rotation axis and is coordinated in a distorted tetrahedral environment in a bidentate fashion by anionic thiolate S and neutral amino N atoms of two 2-[(dimethylamino)methyl]benzenethiolate ligands. All the molecules are in the form. The chosen crystal can thus be considered enantiomerically pure. Intermolecular C-H...π contacts connect the molecules into a two-dimensional network.

AB - In the title compound, [Zn(C9H12NS)2], the ZnII center is located on a twofold rotation axis and is coordinated in a distorted tetrahedral environment in a bidentate fashion by anionic thiolate S and neutral amino N atoms of two 2-[(dimethylamino)methyl]benzenethiolate ligands. All the molecules are in the form. The chosen crystal can thus be considered enantiomerically pure. Intermolecular C-H...π contacts connect the molecules into a two-dimensional network.

M3 - Article

SN - 1600-5368

VL - 63

SP - m1847

JO - Acta crystallographica. Section E, Structure reports

JF - Acta crystallographica. Section E, Structure reports

IS - 7

ER -