Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands

M.A.H. Moelands; S. Nijsse; E. Folkertsma; B. de Bruin; M. Lutz; A.L. Spek; R.J.M. Klein Gebbink

doi:10.1021/ic400096e

Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands

M.A.H. Moelands, S. Nijsse, E. Folkertsma, B. de Bruin, M. Lutz, A.L. Spek, R.J.M. Klein Gebbink

Sub Crystal and Structural Chemistry

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

A series of mononuclear Fe(II) triflate complexes based on the 3,3-bis(1-alkylimidazole-2-yl)propionate ester (BAIP) ligand scaffold are reported. Variation of the steric and electronic properties of the BAIP ligand, a mimic of the 2-His-1-carboxylate facial triad found in mononuclear-nonheme iron enzmyes, provided insight into its coordination flexibility and structural demands as a facial ligand. The Fe(II) complexes were investigated as catalysts in the epoxidation/dihydroxylation of olefins.

Original language	English
Pages (from-to)	7394-7410
Number of pages	17
Journal	Inorganic Chemistry
Volume	52
Issue number	13
DOIs	https://doi.org/10.1021/ic400096e
Publication status	Published - 2013

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title = "Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands",

abstract = "A series of mononuclear Fe(II) triflate complexes based on the 3,3-bis(1-alkylimidazole-2-yl)propionate ester (BAIP) ligand scaffold are reported. Variation of the steric and electronic properties of the BAIP ligand, a mimic of the 2-His-1-carboxylate facial triad found in mononuclear-nonheme iron enzmyes, provided insight into its coordination flexibility and structural demands as a facial ligand. The Fe(II) complexes were investigated as catalysts in the epoxidation/dihydroxylation of olefins.",

author = "M.A.H. Moelands and S. Nijsse and E. Folkertsma and {de Bruin}, B. and M. Lutz and A.L. Spek and {Klein Gebbink}, R.J.M.",

year = "2013",

doi = "10.1021/ic400096e",

language = "English",

volume = "52",

pages = "7394--7410",

journal = "Inorganic Chemistry",

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T1 - Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands

AU - Moelands, M.A.H.

AU - Nijsse, S.

AU - Folkertsma, E.

AU - de Bruin, B.

AU - Lutz, M.

AU - Spek, A.L.

AU - Klein Gebbink, R.J.M.

PY - 2013

Y1 - 2013

N2 - A series of mononuclear Fe(II) triflate complexes based on the 3,3-bis(1-alkylimidazole-2-yl)propionate ester (BAIP) ligand scaffold are reported. Variation of the steric and electronic properties of the BAIP ligand, a mimic of the 2-His-1-carboxylate facial triad found in mononuclear-nonheme iron enzmyes, provided insight into its coordination flexibility and structural demands as a facial ligand. The Fe(II) complexes were investigated as catalysts in the epoxidation/dihydroxylation of olefins.

AB - A series of mononuclear Fe(II) triflate complexes based on the 3,3-bis(1-alkylimidazole-2-yl)propionate ester (BAIP) ligand scaffold are reported. Variation of the steric and electronic properties of the BAIP ligand, a mimic of the 2-His-1-carboxylate facial triad found in mononuclear-nonheme iron enzmyes, provided insight into its coordination flexibility and structural demands as a facial ligand. The Fe(II) complexes were investigated as catalysts in the epoxidation/dihydroxylation of olefins.

U2 - 10.1021/ic400096e

DO - 10.1021/ic400096e

M3 - Article

SN - 0020-1669

VL - 52

SP - 7394

EP - 7410

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands

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