Atropisomeric phosphinines: design and synthesis

C. Müller; E.A. Pidko; D. Totev; M. Lutz; A.L. Spek; R.A. van Santen; D. Vogt

Atropisomeric phosphinines: design and synthesis

C. Müller, E.A. Pidko, D. Totev, M. Lutz, A.L. Spek, R.A. van Santen, D. Vogt

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Abstract

The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.

Original language	Undefined/Unknown
Pages (from-to)	5372-5375
Number of pages	4
Journal	Dalton Transactions
Volume	2007
Issue number	46
Publication status	Published - 2007

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Cite this

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title = "Atropisomeric phosphinines: design and synthesis",

abstract = "The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.",

author = "C. M{\"u}ller and E.A. Pidko and D. Totev and M. Lutz and A.L. Spek and {van Santen}, R.A. and D. Vogt",

year = "2007",

language = "Undefined/Unknown",

volume = "2007",

pages = "5372--5375",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

number = "46",

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T1 - Atropisomeric phosphinines: design and synthesis

AU - Müller, C.

AU - Pidko, E.A.

AU - Totev, D.

AU - Lutz, M.

AU - Spek, A.L.

AU - van Santen, R.A.

AU - Vogt, D.

PY - 2007

Y1 - 2007

N2 - The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.

AB - The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.

M3 - Article

SN - 1477-9226

VL - 2007

SP - 5372

EP - 5375

JO - Dalton Transactions

JF - Dalton Transactions

IS - 46

ER -