Atom transfer polymerization of methyl methacrylate initiated by carbosilane dendritic species

Neides J. Hovestad; Johann T B H Jastrzebski; Gerard Van Koten; Stefan A F Bon; Carl Waterson; David M. Haddleton

Atom transfer polymerization of methyl methacrylate initiated by carbosilane dendritic species

Neides J. Hovestad, Johann T B H Jastrzebski, Gerard Van Koten, Stefan A F Bon, Carl Waterson, David M. Haddleton

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic › peer-review

Abstract

A range of carbosilane dendrimers which have been functionalized with a tertiary bromide species and, subsequently, polymerized through atom transfer polymerization using methyl methacrylate (MMA) as monomer is reported. Schiff's base ligands were used for Cu(I)Br complexation. The use of these ligands have proven to be extremely effective for atom transfer polymerization of methacrylates and other vinyl monomers. The influence of the dendritic initiators on the molecular weight distributions of the polymer material produced throughout the living radical polymerization process was investigated.

Original language	English
Title of host publication	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Publisher	American Chemical Society
Pages	393-394
Number of pages	2
Volume	40
Edition	2
Publication status	Published - Aug 1999

Cite this

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title = "Atom transfer polymerization of methyl methacrylate initiated by carbosilane dendritic species",

abstract = "A range of carbosilane dendrimers which have been functionalized with a tertiary bromide species and, subsequently, polymerized through atom transfer polymerization using methyl methacrylate (MMA) as monomer is reported. Schiff's base ligands were used for Cu(I)Br complexation. The use of these ligands have proven to be extremely effective for atom transfer polymerization of methacrylates and other vinyl monomers. The influence of the dendritic initiators on the molecular weight distributions of the polymer material produced throughout the living radical polymerization process was investigated.",

author = "Hovestad, {Neides J.} and Jastrzebski, {Johann T B H} and {Van Koten}, Gerard and Bon, {Stefan A F} and Carl Waterson and Haddleton, {David M.}",

year = "1999",

month = aug,

language = "English",

volume = "40",

pages = "393--394",

booktitle = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

publisher = "American Chemical Society",

address = "United States",

edition = "2",

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Atom transfer polymerization of methyl methacrylate initiated by carbosilane dendritic species. / Hovestad, Neides J.; Jastrzebski, Johann T B H; Van Koten, Gerard et al.
American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 40 2. ed. American Chemical Society, 1999. p. 393-394.

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic › peer-review

TY - CHAP

T1 - Atom transfer polymerization of methyl methacrylate initiated by carbosilane dendritic species

AU - Hovestad, Neides J.

AU - Jastrzebski, Johann T B H

AU - Van Koten, Gerard

AU - Bon, Stefan A F

AU - Waterson, Carl

AU - Haddleton, David M.

PY - 1999/8

Y1 - 1999/8

N2 - A range of carbosilane dendrimers which have been functionalized with a tertiary bromide species and, subsequently, polymerized through atom transfer polymerization using methyl methacrylate (MMA) as monomer is reported. Schiff's base ligands were used for Cu(I)Br complexation. The use of these ligands have proven to be extremely effective for atom transfer polymerization of methacrylates and other vinyl monomers. The influence of the dendritic initiators on the molecular weight distributions of the polymer material produced throughout the living radical polymerization process was investigated.

AB - A range of carbosilane dendrimers which have been functionalized with a tertiary bromide species and, subsequently, polymerized through atom transfer polymerization using methyl methacrylate (MMA) as monomer is reported. Schiff's base ligands were used for Cu(I)Br complexation. The use of these ligands have proven to be extremely effective for atom transfer polymerization of methacrylates and other vinyl monomers. The influence of the dendritic initiators on the molecular weight distributions of the polymer material produced throughout the living radical polymerization process was investigated.

UR - http://www.scopus.com/inward/record.url?scp=0032647253&partnerID=8YFLogxK

M3 - Chapter

AN - SCOPUS:0032647253

VL - 40

SP - 393

EP - 394

BT - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

PB - American Chemical Society

ER -

Atom transfer polymerization of methyl methacrylate initiated by carbosilane dendritic species

Abstract

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