Another silver complex of 1,3-dibenzylimidazol-2-ylidene: solution and solid-state structures

J. Berding; H. Kooijman; A.L. Spek; E. Bouwman

Another silver complex of 1,3-dibenzylimidazol-2-ylidene: solution and solid-state structures

J. Berding, H. Kooijman, A.L. Spek, E. Bouwman

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Abstract

The reaction of 1,3-dibenzylimidazolium bromide (Bn2Im · HBr) with silver(I) oxide yields the dinuclear compound {(Bn2Im)AgBr}2 as determined with X-ray crystallography. The structure turned out to differ significantly from the mononuclear complex (Bn2Im)2AgBr that was reported during our studies. It appears that the various structures are a result of different crystallization conditions. A new classification of solid-state structures of these and other silver(I) complexes containing monodentate N-heterocyclic carbenes is presented.

Original language	Undefined/Unknown
Pages (from-to)	2217-2221
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	694
Issue number	14
Publication status	Published - 2009

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Cite this

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title = "Another silver complex of 1,3-dibenzylimidazol-2-ylidene: solution and solid-state structures",

abstract = "The reaction of 1,3-dibenzylimidazolium bromide (Bn2Im · HBr) with silver(I) oxide yields the dinuclear compound {(Bn2Im)AgBr}2 as determined with X-ray crystallography. The structure turned out to differ significantly from the mononuclear complex (Bn2Im)2AgBr that was reported during our studies. It appears that the various structures are a result of different crystallization conditions. A new classification of solid-state structures of these and other silver(I) complexes containing monodentate N-heterocyclic carbenes is presented.",

author = "J. Berding and H. Kooijman and A.L. Spek and E. Bouwman",

note = "Issue Title: N-Heterocyclic Carbenes",

year = "2009",

language = "Undefined/Unknown",

volume = "694",

pages = "2217--2221",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - Another silver complex of 1,3-dibenzylimidazol-2-ylidene: solution and solid-state structures

AU - Berding, J.

AU - Kooijman, H.

AU - Spek, A.L.

AU - Bouwman, E.

N1 - Issue Title: N-Heterocyclic Carbenes

PY - 2009

Y1 - 2009

N2 - The reaction of 1,3-dibenzylimidazolium bromide (Bn2Im · HBr) with silver(I) oxide yields the dinuclear compound {(Bn2Im)AgBr}2 as determined with X-ray crystallography. The structure turned out to differ significantly from the mononuclear complex (Bn2Im)2AgBr that was reported during our studies. It appears that the various structures are a result of different crystallization conditions. A new classification of solid-state structures of these and other silver(I) complexes containing monodentate N-heterocyclic carbenes is presented.

AB - The reaction of 1,3-dibenzylimidazolium bromide (Bn2Im · HBr) with silver(I) oxide yields the dinuclear compound {(Bn2Im)AgBr}2 as determined with X-ray crystallography. The structure turned out to differ significantly from the mononuclear complex (Bn2Im)2AgBr that was reported during our studies. It appears that the various structures are a result of different crystallization conditions. A new classification of solid-state structures of these and other silver(I) complexes containing monodentate N-heterocyclic carbenes is presented.

M3 - Article

SN - 0022-328X

VL - 694

SP - 2217

EP - 2221

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 14

ER -