A Multispectroscopic Study of 3d Orbitals in Cobalt Carboxylates: The High Sensitivity of 2p3d Resonant X-ray Emission Spectroscopy to the Ligand Field

Matti M. van Schooneveld; Robert W. Gosselink; Tamara M. Eggenhuisen; Mustafa Al Samarai; Claude Monney; Kejin J. Zhou; Thorsten Schmitt; Frank M. F. de Groot

doi:10.1002/anie.201204855

A Multispectroscopic Study of 3d Orbitals in Cobalt Carboxylates: The High Sensitivity of 2p3d Resonant X-ray Emission Spectroscopy to the Ligand Field

Matti M. van Schooneveld^*
, Robert W. Gosselink
, Tamara M. Eggenhuisen
, Mustafa Al Samarai
, Claude Monney
, Kejin J. Zhou
, Thorsten Schmitt
, Frank M. F. de Groot

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Original language	English
Pages (from-to)	1170-1174
Number of pages	5
Journal	Angewandte Chemie-International Edition
Volume	52
Issue number	4
DOIs	https://doi.org/10.1002/anie.201204855
Publication status	Published - 2013

Funding

We thank V.N. Strocov, P.S. Peijzel, and K.P. de Jong for support and discussions, and NWO-CW VICI for financial support. XAS/RXES were performed at the ADRESS beamline of the SLS using the SAXES instrument jointly built by PSI, Switzerland and Politecnico di Milano, Italy.

Keywords

cobalt
ligand field theory
photochemistry
UV/Vis spectroscopy
X-ray emission spectroscopy
D-D EXCITATIONS
FLUORESCENCE SPECTROSCOPY
SCATTERING
SPECTRA
SYSTEMS

Access to Document

10.1002/anie.201204855

van-Schooneveld_et_al-2013-Angewandte_Chemie_International_EditionFinal published version, 1.2 MB

Cite this

van Schooneveld, M. M., Gosselink, R. W., Eggenhuisen, T. M., Al Samarai, M., Monney, C., Zhou, K. J., Schmitt, T., & de Groot, F. M. F. (2013). A Multispectroscopic Study of 3d Orbitals in Cobalt Carboxylates: The High Sensitivity of 2p3d Resonant X-ray Emission Spectroscopy to the Ligand Field. Angewandte Chemie-International Edition, 52(4), 1170-1174. https://doi.org/10.1002/anie.201204855

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keywords = "cobalt, ligand field theory, photochemistry, UV/Vis spectroscopy, X-ray emission spectroscopy, D-D EXCITATIONS, FLUORESCENCE SPECTROSCOPY, SCATTERING, SPECTRA, SYSTEMS",

author = "\{van Schooneveld\}, \{Matti M.\} and Gosselink, \{Robert W.\} and Eggenhuisen, \{Tamara M.\} and \{Al Samarai\}, Mustafa and Claude Monney and Zhou, \{Kejin J.\} and Thorsten Schmitt and \{de Groot\}, \{Frank M. F.\}",

year = "2013",

doi = "10.1002/anie.201204855",

language = "English",

volume = "52",

pages = "1170--1174",

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van Schooneveld, MM, Gosselink, RW, Eggenhuisen, TM, Al Samarai, M, Monney, C, Zhou, KJ, Schmitt, T & de Groot, FMF 2013, 'A Multispectroscopic Study of 3d Orbitals in Cobalt Carboxylates: The High Sensitivity of 2p3d Resonant X-ray Emission Spectroscopy to the Ligand Field', Angewandte Chemie-International Edition, vol. 52, no. 4, pp. 1170-1174. https://doi.org/10.1002/anie.201204855

A Multispectroscopic Study of 3d Orbitals in Cobalt Carboxylates: The High Sensitivity of 2p3d Resonant X-ray Emission Spectroscopy to the Ligand Field. / van Schooneveld, Matti M.; Gosselink, Robert W.; Eggenhuisen, Tamara M. et al.
In: Angewandte Chemie-International Edition, Vol. 52, No. 4, 2013, p. 1170-1174.

Research output: Contribution to journal › Article › Academic › peer-review

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AU - Al Samarai, Mustafa

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AU - Zhou, Kejin J.

AU - Schmitt, Thorsten

AU - de Groot, Frank M. F.

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