A methodology for the heuristic optimization of solvent-based CO₂ capture processes when applied to new flue gas compositions: A case study of the Chilled Ammonia Process for capture in cement plants

Solvent-based post-combustion CO₂ capture technologies are key to timely decrease industrial CO₂ emissions. However, the flue gas composition differs among different industries so that different optimal operating conditions are expected. This work provides a methodology to determine the operating conditions that minimize energy consumption and maximize productivity of the capture process, for given flue gas composition and process specifications, while keeping the time required for process development at a minimal level. Firstly, it carries out a comprehensive selection and calibration of the model. Secondly, it applies a step-wise heuristic optimization procedure. In this work, this methodology has been demonstrated by means of the Chilled Ammonia Process (CAP) applied to cement plants. The optimal CAP operation has led to reboiler duties as low as 2.1 MJ_th kg_CO2captured^-1, while maintaining the productivity of the CO₂ absorber, thus the column height, at values similar to those typical of the power plant application.