Abstract
In this contribution we present the direct conversion of sodium phosphinate (NaH2PO2·H2O) to symmetrical sodium diarylphosphinates and their corresponding acids by using palladium catalysis. This route eliminates the need for chlorinated precursors, such as PCl3 and intermediate alkyl- or ammoniumphosphinates.
Original language | English |
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Pages (from-to) | 434-437 |
Number of pages | 4 |
Journal | European Journal of Organic Chemistry |
Volume | 2017 |
Issue number | 3 |
DOIs | |
Publication status | Published - 18 Jan 2017 |
Externally published | Yes |
Keywords
- Cross-coupling
- Homogeneous catalysis
- Industrial chemistry
- Palladium
- Phosphinates
- Sustainable chemistry