A π-extended β-diketiminate ligand via a templated Scholl approach

Lars Killian; Martin Lutz; Arnaud Thevenon

doi:10.1039/d4cc01627k

A π-extended β-diketiminate ligand via a templated Scholl approach

Lars Killian, Martin Lutz, Arnaud Thevenon^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

We report a templated Scholl oxidation strategy for the preparation of the first β-diketiminate (BDI) ligands embedded within a 24-electron π-system backbone. The resulting benzo[f,g]tetracene BDI ligand was coordinated to a zinc centre and electrochemical studies showed the redox active nature of the ligand.

Original language	English
Pages (from-to)	6663–6666
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	52
Early online date	6 Jun 2024
DOIs	https://doi.org/10.1039/d4cc01627k
Publication status	Published - 2024

Bibliographical note

Publisher Copyright:
© 2024 The Royal Society of Chemistry

Funding

A. T. thanks the Dutch Research Council (NWO) for funding via Veni grant (Veni.212.039) and Utrecht University for financial support. The X-ray diffractometer has been financed by NWO.

Funders	Funder number
Dutch Research Council (NWO) via Veni grant	Veni.212.039
Utrecht University
NWO

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d4cc01627kFinal published version, 967 KBLicence: CC BY

Cite this

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abstract = "We report a templated Scholl oxidation strategy for the preparation of the first β-diketiminate (BDI) ligands embedded within a 24-electron π-system backbone. The resulting benzo[f,g]tetracene BDI ligand was coordinated to a zinc centre and electrochemical studies showed the redox active nature of the ligand.",

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AU - Lutz, Martin

AU - Thevenon, Arnaud

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AB - We report a templated Scholl oxidation strategy for the preparation of the first β-diketiminate (BDI) ligands embedded within a 24-electron π-system backbone. The resulting benzo[f,g]tetracene BDI ligand was coordinated to a zinc centre and electrochemical studies showed the redox active nature of the ligand.

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DO - 10.1039/d4cc01627k

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EP - 6666

JO - Chemical Communications

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ER -

A π-extended β-diketiminate ligand via a templated Scholl approach

Abstract

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