4f-5d Transitions of Tb3+ in Cs2NaYF6: The Effect of Distortion of the Excited-State Configuration

C.K. Duan; P.A. Tanner; A. Meijerink; V. Makhov

doi:10.1021/jp205011v

4f-5d Transitions of Tb3+ in Cs2NaYF6: The Effect of Distortion of the Excited-State Configuration

C.K. Duan, P.A. Tanner, A. Meijerink, V. Makhov

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Abstract

The low-temperature absorption and excitation spectra of interconfigurational 4f–5d transitions of Tb3+ in a cubic fluoride host demonstrate the appearance of a first-order linear Jahn–Teller effect for the high-spin excited states of the excited electronic configuration 4f75d involving 5d t2g orbitals. The τ2g mode is observed to be responsible for the splitting of the otherwise degenerate 5d t2g orbitals.

Original language	English
Pages (from-to)	9188-9191
Number of pages	4
Journal	Journal of Physical Chemistry A
Volume	115
Issue number	33
DOIs	https://doi.org/10.1021/jp205011v
Publication status	Published - 2011

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title = "4f-5d Transitions of Tb3+ in Cs2NaYF6: The Effect of Distortion of the Excited-State Configuration",

abstract = "The low-temperature absorption and excitation spectra of interconfigurational 4f–5d transitions of Tb3+ in a cubic fluoride host demonstrate the appearance of a first-order linear Jahn–Teller effect for the high-spin excited states of the excited electronic configuration 4f75d involving 5d t2g orbitals. The τ2g mode is observed to be responsible for the splitting of the otherwise degenerate 5d t2g orbitals.",

author = "C.K. Duan and P.A. Tanner and A. Meijerink and V. Makhov",

year = "2011",

doi = "10.1021/jp205011v",

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journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

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T1 - 4f-5d Transitions of Tb3+ in Cs2NaYF6: The Effect of Distortion of the Excited-State Configuration

AU - Duan, C.K.

AU - Tanner, P.A.

AU - Meijerink, A.

AU - Makhov, V.

PY - 2011

Y1 - 2011

N2 - The low-temperature absorption and excitation spectra of interconfigurational 4f–5d transitions of Tb3+ in a cubic fluoride host demonstrate the appearance of a first-order linear Jahn–Teller effect for the high-spin excited states of the excited electronic configuration 4f75d involving 5d t2g orbitals. The τ2g mode is observed to be responsible for the splitting of the otherwise degenerate 5d t2g orbitals.

AB - The low-temperature absorption and excitation spectra of interconfigurational 4f–5d transitions of Tb3+ in a cubic fluoride host demonstrate the appearance of a first-order linear Jahn–Teller effect for the high-spin excited states of the excited electronic configuration 4f75d involving 5d t2g orbitals. The τ2g mode is observed to be responsible for the splitting of the otherwise degenerate 5d t2g orbitals.

U2 - 10.1021/jp205011v

DO - 10.1021/jp205011v

M3 - Article

SN - 1089-5639

VL - 115

SP - 9188

EP - 9191

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 33

ER -

4f-5d Transitions of Tb3+ in Cs2NaYF6: The Effect of Distortion of the Excited-State Configuration

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