2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i)

A. Campos Carrasco; E.A. Pidko; A. M. Masdeu-Bultó; M. Lutz; A.L. Spek; D. Vogt; C. Müller

doi:10.1039/c0nj00030b

2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i)

A. Campos Carrasco, E.A. Pidko, A. M. Masdeu-Bultó, M. Lutz, A.L. Spek, D. Vogt, C. Müller

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Abstract

The coordination chemistry of the bidentate P,N hybrid ligand 2-(2′-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2′-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

Original language	English
Pages (from-to)	1547-1550
Number of pages	4
Journal	New Journal of Chemistry
Volume	34
Issue number	8
DOIs	https://doi.org/10.1039/c0nj00030b
Publication status	Published - 2010

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title = "2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i)",

abstract = "The coordination chemistry of the bidentate P,N hybrid ligand 2-(2′-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2′-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.",

author = "{Campos Carrasco}, A. and E.A. Pidko and Masdeu-Bult{\'o}, {A. M.} and M. Lutz and A.L. Spek and D. Vogt and C. M{\"u}ller",

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doi = "10.1039/c0nj00030b",

language = "English",

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pages = "1547--1550",

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T1 - 2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i)

AU - Campos Carrasco, A.

AU - Pidko, E.A.

AU - Masdeu-Bultó, A. M.

AU - Lutz, M.

AU - Spek, A.L.

AU - Vogt, D.

AU - Müller, C.

PY - 2010

Y1 - 2010

N2 - The coordination chemistry of the bidentate P,N hybrid ligand 2-(2′-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2′-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

AB - The coordination chemistry of the bidentate P,N hybrid ligand 2-(2′-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2′-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

U2 - 10.1039/c0nj00030b

DO - 10.1039/c0nj00030b

M3 - Article

SN - 1369-9261

VL - 34

SP - 1547

EP - 1550

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 8

ER -

2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i)

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