1s2p Resonant Inelastic X-ray Scattering of Iron Oxides

FMF de Groot; P Glatzel; U Bergmann; PA van Aken; RA Barrea; S Klemme; M Havecker; A Knop-Gericke; WM Heijboer; BM Weckhuysen

doi:10.1021/jp054006s

1s2p Resonant Inelastic X-ray Scattering of Iron Oxides

FMF de Groot, P Glatzel, U Bergmann, PA van Aken, RA Barrea, S Klemme, M Havecker, A Knop-Gericke, WM Heijboer, BM Weckhuysen

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

1s2p resonant inelastic X-ray scattering (RTXS) spectroscopy has been measured for a series of iron oxides, including octahedral and tetrahedral Fe(II) and Fe(III) systems. Their spectral shapes have been analyzed and explained using crystal-field multiplet simulations. The RIXS planes and the K-edge and L-edge X-ray absorption spectra related to these RIXS planes will be discussed with respect to their analytical opportunities. It is concluded that the full power and possibilities of 1s2p RIXS needs an overall resolution of 0.3 eV. This will yield a technique with more detailed information than K-edge and L-edge X-ray absorption combined, obtained in a single experiment. Another major advantage is that 1s2p RIXS involves only hard X-rays, and experiments under essentially any condition and on any system are feasible.

Original language	English
Pages (from-to)	20751-20762
Number of pages	12
Journal	Journal of Physical Chemistry. B
Volume	109
Issue number	44
DOIs	https://doi.org/10.1021/jp054006s
Publication status	Published - 10 Nov 2005

Keywords

ABSORPTION-SPECTROSCOPY
K-EDGE
PRE-EDGE
IN-SITU
ELECTRONIC-STRUCTURE
XANES CALCULATIONS
ENERGY RESOLUTION
OXIDATION-STATES
PHOTOSYSTEM-II
TRANSITION

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title = "1s2p Resonant Inelastic X-ray Scattering of Iron Oxides",

abstract = "1s2p resonant inelastic X-ray scattering (RTXS) spectroscopy has been measured for a series of iron oxides, including octahedral and tetrahedral Fe(II) and Fe(III) systems. Their spectral shapes have been analyzed and explained using crystal-field multiplet simulations. The RIXS planes and the K-edge and L-edge X-ray absorption spectra related to these RIXS planes will be discussed with respect to their analytical opportunities. It is concluded that the full power and possibilities of 1s2p RIXS needs an overall resolution of 0.3 eV. This will yield a technique with more detailed information than K-edge and L-edge X-ray absorption combined, obtained in a single experiment. Another major advantage is that 1s2p RIXS involves only hard X-rays, and experiments under essentially any condition and on any system are feasible.",

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author = "{de Groot}, FMF and P Glatzel and U Bergmann and {van Aken}, PA and RA Barrea and S Klemme and M Havecker and A Knop-Gericke and WM Heijboer and BM Weckhuysen",

year = "2005",

month = nov,

day = "10",

doi = "10.1021/jp054006s",

language = "English",

volume = "109",

pages = "20751--20762",

journal = "Journal of Physical Chemistry. B",

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TY - JOUR

T1 - 1s2p Resonant Inelastic X-ray Scattering of Iron Oxides

AU - de Groot, FMF

AU - Glatzel, P

AU - Bergmann, U

AU - van Aken, PA

AU - Barrea, RA

AU - Klemme, S

AU - Havecker, M

AU - Knop-Gericke, A

AU - Heijboer, WM

AU - Weckhuysen, BM

PY - 2005/11/10

Y1 - 2005/11/10

N2 - 1s2p resonant inelastic X-ray scattering (RTXS) spectroscopy has been measured for a series of iron oxides, including octahedral and tetrahedral Fe(II) and Fe(III) systems. Their spectral shapes have been analyzed and explained using crystal-field multiplet simulations. The RIXS planes and the K-edge and L-edge X-ray absorption spectra related to these RIXS planes will be discussed with respect to their analytical opportunities. It is concluded that the full power and possibilities of 1s2p RIXS needs an overall resolution of 0.3 eV. This will yield a technique with more detailed information than K-edge and L-edge X-ray absorption combined, obtained in a single experiment. Another major advantage is that 1s2p RIXS involves only hard X-rays, and experiments under essentially any condition and on any system are feasible.

AB - 1s2p resonant inelastic X-ray scattering (RTXS) spectroscopy has been measured for a series of iron oxides, including octahedral and tetrahedral Fe(II) and Fe(III) systems. Their spectral shapes have been analyzed and explained using crystal-field multiplet simulations. The RIXS planes and the K-edge and L-edge X-ray absorption spectra related to these RIXS planes will be discussed with respect to their analytical opportunities. It is concluded that the full power and possibilities of 1s2p RIXS needs an overall resolution of 0.3 eV. This will yield a technique with more detailed information than K-edge and L-edge X-ray absorption combined, obtained in a single experiment. Another major advantage is that 1s2p RIXS involves only hard X-rays, and experiments under essentially any condition and on any system are feasible.

KW - ABSORPTION-SPECTROSCOPY

KW - K-EDGE

KW - PRE-EDGE

KW - IN-SITU

KW - ELECTRONIC-STRUCTURE

KW - XANES CALCULATIONS

KW - ENERGY RESOLUTION

KW - OXIDATION-STATES

KW - PHOTOSYSTEM-II

KW - TRANSITION

U2 - 10.1021/jp054006s

DO - 10.1021/jp054006s

M3 - Article

SN - 1520-6106

VL - 109

SP - 20751

EP - 20762

JO - Journal of Physical Chemistry. B

JF - Journal of Physical Chemistry. B

IS - 44

ER -

1s2p Resonant Inelastic X-ray Scattering of Iron Oxides

Abstract

Keywords

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