1,1'-Bis(ferrocenylphenylphosphino)-ferrocene

L.S. von Chrzanowski; M. Lutz; A.L. Spek

1,1'-Bis(ferrocenylphenylphosphino)-ferrocene

L.S. von Chrzanowski, M. Lutz, A.L. Spek

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Abstract

In the title compound, [Fe3(C5H5)2(C16H13P)2], two (C6H5)P-[(C5H4)Fe(C5H5)](C5H4) units are bridged by an Fe atom, located on an inversion center, giving a central third ferrocene unit. Each Fe atom is coordinated by two cyclopentadienyl rings in a parallel sandwich fashion, with twisted conformations. The geometry of the phosphine P atom is pseudotetrahedral, defined by a phenyl ring, two cyclopentadienyl rings and an electron pair.

Original language	Undefined/Unknown
Pages (from-to)	m2098
Number of pages	16
Journal	Acta crystallographica. Section E, Structure reports
Volume	E63
Publication status	Published - 2007

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@article{6994ddad52884685abd8af32c1ca9c50,

title = "1,1'-Bis(ferrocenylphenylphosphino)-ferrocene",

abstract = "In the title compound, [Fe3(C5H5)2(C16H13P)2], two (C6H5)P-[(C5H4)Fe(C5H5)](C5H4) units are bridged by an Fe atom, located on an inversion center, giving a central third ferrocene unit. Each Fe atom is coordinated by two cyclopentadienyl rings in a parallel sandwich fashion, with twisted conformations. The geometry of the phosphine P atom is pseudotetrahedral, defined by a phenyl ring, two cyclopentadienyl rings and an electron pair.",

author = "{von Chrzanowski}, L.S. and M. Lutz and A.L. Spek",

year = "2007",

language = "Undefined/Unknown",

volume = "E63",

pages = "m2098",

journal = "Acta crystallographica. Section E, Structure reports",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - 1,1'-Bis(ferrocenylphenylphosphino)-ferrocene

AU - von Chrzanowski, L.S.

AU - Lutz, M.

AU - Spek, A.L.

PY - 2007

Y1 - 2007

N2 - In the title compound, [Fe3(C5H5)2(C16H13P)2], two (C6H5)P-[(C5H4)Fe(C5H5)](C5H4) units are bridged by an Fe atom, located on an inversion center, giving a central third ferrocene unit. Each Fe atom is coordinated by two cyclopentadienyl rings in a parallel sandwich fashion, with twisted conformations. The geometry of the phosphine P atom is pseudotetrahedral, defined by a phenyl ring, two cyclopentadienyl rings and an electron pair.

AB - In the title compound, [Fe3(C5H5)2(C16H13P)2], two (C6H5)P-[(C5H4)Fe(C5H5)](C5H4) units are bridged by an Fe atom, located on an inversion center, giving a central third ferrocene unit. Each Fe atom is coordinated by two cyclopentadienyl rings in a parallel sandwich fashion, with twisted conformations. The geometry of the phosphine P atom is pseudotetrahedral, defined by a phenyl ring, two cyclopentadienyl rings and an electron pair.

M3 - Article

SN - 1600-5368

VL - E63

SP - m2098

JO - Acta crystallographica. Section E, Structure reports

JF - Acta crystallographica. Section E, Structure reports

ER -