α-Tris(2,4-pentanedionato-k2O,O')aluminium(III) at 240, 210, 180, 150 and 110 K: a new δ phase at 110 K

L.S. von Chrzanowski; M. Lutz; A.L. Spek

α-Tris(2,4-pentanedionato-k2O,O')aluminium(III) at 240, 210, 180, 150 and 110 K: a new δ phase at 110 K

L.S. von Chrzanowski, M. Lutz, A.L. Spek

Dep Scheikunde

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The crystal structure of the title compound, [Al(C5H7O2)3], has been investigated by a multi-temperature measurement to provide information on thermal vibrations and disorder in the structure. At 110 K, the structure of a new δ polymorph could be determined. A disorder-order phase transition takes place between 150 and 110 K and is klassengleich. The unit-cell volume increases by a factor of three and the diffraction pattern shows weak supercell reflections.

Original language	Undefined/Unknown
Pages (from-to)	m129-m134
Number of pages	6
Journal	Acta Crystallographica. Section C, Crystal Structure Communications
Volume	C63
Publication status	Published - 2007

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title = "α-Tris(2,4-pentanedionato-k2O,O')aluminium(III) at 240, 210, 180, 150 and 110 K: a new δ phase at 110 K",

abstract = "The crystal structure of the title compound, [Al(C5H7O2)3], has been investigated by a multi-temperature measurement to provide information on thermal vibrations and disorder in the structure. At 110 K, the structure of a new δ polymorph could be determined. A disorder-order phase transition takes place between 150 and 110 K and is klassengleich. The unit-cell volume increases by a factor of three and the diffraction pattern shows weak supercell reflections.",

author = "{von Chrzanowski}, L.S. and M. Lutz and A.L. Spek",

year = "2007",

language = "Undefined/Unknown",

volume = "C63",

pages = "m129--m134",

journal = "Acta Crystallographica. Section C, Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - α-Tris(2,4-pentanedionato-k2O,O')aluminium(III) at 240, 210, 180, 150 and 110 K: a new δ phase at 110 K

AU - von Chrzanowski, L.S.

AU - Lutz, M.

AU - Spek, A.L.

PY - 2007

Y1 - 2007

N2 - The crystal structure of the title compound, [Al(C5H7O2)3], has been investigated by a multi-temperature measurement to provide information on thermal vibrations and disorder in the structure. At 110 K, the structure of a new δ polymorph could be determined. A disorder-order phase transition takes place between 150 and 110 K and is klassengleich. The unit-cell volume increases by a factor of three and the diffraction pattern shows weak supercell reflections.

AB - The crystal structure of the title compound, [Al(C5H7O2)3], has been investigated by a multi-temperature measurement to provide information on thermal vibrations and disorder in the structure. At 110 K, the structure of a new δ polymorph could be determined. A disorder-order phase transition takes place between 150 and 110 K and is klassengleich. The unit-cell volume increases by a factor of three and the diffraction pattern shows weak supercell reflections.

M3 - Article

SN - 0108-2701

VL - C63

SP - m129-m134

JO - Acta Crystallographica. Section C, Crystal Structure Communications

JF - Acta Crystallographica. Section C, Crystal Structure Communications

ER -