Inorganic Chemistry and Catalysis

2025

Catalytic Pyrolysis of Polyethylene with Microporous and Mesoporous Materials: Assessing Performance and Mechanistic Understanding

van de Minkelis, J. H., Hergesell, A. H., van der Waal, J. C., Altink, R. M., Vollmer, I. & Weckhuysen, B. M., 1 Apr 2025, In: ChemSusChem. 18, 7, e202401141.

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Chitosan microsphere-supported catalysts: design, synthesis and optimization for ethylene polymerization

Dorresteijn, J. M., Conradi, R., Mandemaker, L. D. B., Schnabl, K., Cirriez, V., Welle, A., Curulla-Ferré, D., Meirer, F., Vogt, E. T. C. & Weckhuysen, B. M., 7 Jan 2025, In: Materials Advances. 6, 1, p. 201-213 13 p.

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Correlating Heterogeneities in Support Fragmentation to Polymer Morphology in Metallocene-Based Propylene Polymerization Catalysis

Dorresteijn, J. M., Valadian, R., Ji, Y., Zanoni, S., Bossers, K. W., Nikolopoulos, N., Cirriez, V., Welle, A., Curulla-Ferré, D., Vogt, E. T. C., Meirer, F. & Weckhuysen, B. M., 6 Feb 2025, In: ChemCatChem. 17, 3, e202401183.

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Diffusion in nanoporous materials with special consideration of the measurement of determining parameters (IUPAC Technical Report)

Kaerger, J., Valiullin, R., Brandani, S., Caro, J., Chmelik, C., Chmelka, B. F., Coppens, M.-O., Farooq, S., Freude, D., Jobic, H., Kruteva, M., Mangano, E., Pini, R., Price, W. S., Rajendran, A., Ravikovitch, P. I., Sastre, G., Snurr, R. Q., Stepanov, A. G. & Vasenkov, S. & 2 others, Wang, Y. & Weckhuysen, B. M., 2025, In: Pure and Applied Chemistry. 97, 1, p. 1-89 89 p.

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Elucidation of the Co⁴⁺ state with strong charge-transfer effects in charged LiCoO₂ by resonant soft X-ray emission spectroscopy at the Co L₃ edge

Asakura, D., Sudayama, T., Nanba, Y., Hosono, E., Kiuchi, H., Yamazoe, K., Miyawaki, J., Harada, Y., Yamada, A., Wang, R. P. & de Groot, F. M. F., 2025, In: Physical Chemistry Chemical Physics. 27, 8, p. 4092-4098 7 p.

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Engineering Single Ni Sites on 3D Cage-like Cucurbit[n]uril Ligands for Efficient and Selective CO₂ Photocatalytic Reduction

Wang, J., Li, X., Chang, C. H., Zhang, T., Guan, X., Liu, Q., Zhang, L., Wen, P., Tang, I., Zhang, Y., Yang, X., Tang, J. & Lan, Y., 27 Jan 2025, In: Angewandte Chemie - International Edition. 64, 5, e202417384.

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External acidity as performance descriptor in polyolefin cracking using zeolite-based materials

Rejman, S., Reverdy, Z. M., Bör, Z., Louwen, J. N., Rieg, C., Dorresteijn, J. M., van der Waal, J.-K., Vogt, E. T. C., Vollmer, I. & Weckhuysen, B. M., 26 Mar 2025, In: Nature Communications. 16, 1, 2980.

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Highly Antioxidative Lithium Salt Enables High-Voltage Ether Electrolyte for Lithium Metal Battery

He, J., Qi, S., Wang, H., Ma, J. & Artrith, N., 2025, In: ACS Applied Energy Materials. 8, 1, p. 343–354 12 p.

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Highly Dispersed ZnO Sites in a ZnO/ZrO2 Catalyst Promote Carbon Dioxide-to-Methanol Conversion

Zhang, X., Yu, X., Mendes, R. G., Matvija, P., Melcherts, A. E. M., Sun, C., Ye, X., Weckhuysen, B. M. & Monai, M., 21 Jan 2025, In: Angewandte Chemie-International Edition. 64, 4, 11 p., e202416899.

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Insight into the influence of Re and Cl on Ag catalysts in ethylene epoxidation

Keijzer, C. J., Weide, P. T., Helfferich, K. H., Zieciak, J., de Ridder, M., Dalebout, R., Lohr, T. L., Lockemeyer, J. R., van den Brink, P. & de Jongh, P. E., 2025, In: Catalysis Science & Technology. 15, 2, p. 323-333 11 p.

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Multiscale X-ray scattering elucidates activation and deactivation of oxide-derived copper electrocatalysts for CO₂ reduction

de Ruiter, J., Benning, V. R. M., Yang, S., den Hartigh, B. J., Wang, H., Prins, P. T., Dorresteijn, J. M., Janssens, J. C. L., Manna, G., Petukhov, A. V., Weckhuysen, B. M., Rabouw, F. T. & van der Stam, W., 3 Jan 2025, In: Nature Communications. 16, 1, 11 p., 373.

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Operando Luminescence Thermometry for Hydrocarbon Conversion Catalysis: Dealing with Dynamic Changes in Catalyst Optical Properties

Vogel, R., Groefsema, D. W., van den Bulk, M. A., Jacobs, T. S., Prins, P. T., Rabouw, F. T. & Weckhuysen, B. M., 9 Apr 2025, In: ACS applied materials & interfaces. 17, 14, p. 21215–21222

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2024

A binary catalytic system of sulfonated metal–organic frameworks and deep eutectic solvents towards highly efficient synthesis of 5-hydroxymethylfurfural from fructose

Li, M., Huai, L., Zhang, Y., Ma, H., Zhang, P., Xu, F., Zhang, J. & Jiang, L., 1 Aug 2024, In: Chemical Engineering Journal. 493, 152767.

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Alternative nano-lithographic tools for shell-isolated nanoparticle enhanced Raman spectroscopy substrates

Srivastava, K., Jacobs, T. S., Ostendorp, S., Jonker, D., Brzesowsky, F. A., Susarrey-Arce, A., Gardeniers, H., Wilde, G., Weckhuysen, B. M., van den Berg, A., van der Stam, W. & Odijk, M., Apr 2024, In: Nanoscale. 16, 15, p. 7582-7593 12 p.

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Anchoring PdOx clusters on defective alumina for improved catalytic methane oxidation.

Yu, X., Genz, N. S., Mendes, R. G., Ye, X., Meirer, F., Nachtegaal, M., Monai, M. & Weckhuysen, B. M., 1 Aug 2024, In: Nature Communications. 15, 1, 12 p., 6494.

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An Integrated Carbon Dioxide Capture and Methanation Process

Zhang, X., Li, M., Liu, X., Li, A., Deng, Y., Peng, M., Zhang, Y., Vogt, C., Monai, M., Gao, J., Qin, X., Xu, Y., Yu, Q., Wang, M., Wang, G., Jiang, Z., Han, X., Brady, C., Li, W. X. & Zhou, W. & 4 others, Liu, J. X., Xu, B., Weckhuysen, B. M. & Ma, D., 3 May 2024, In: CCS Chemistry. 6, 5, p. 1174-1183 10 p.

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Chitosan as Support Material for Metal-Organic Framework based Catalysts

Jabbour, C. R., Schnabl, K. B., Yan, H., O'Beirn, N. N., Dorresteijn, J. M., Meirer, F., Mandemaker, L. D. B. & Weckhuysen, B. M., 2 Sept 2024, In: ChemPhysChem. 25, 17, e202400154.

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Chlorine Speciation by GC-XSD for the Characterization of Plastic Pyrolysis Oil as a Cracker Feedstock

Giri, A., Yan, H., Emamjomeh, O., Cuoq, F., Kwakkenbos, G., van Zijl, A. & Wong, K., 2024, In: Energy and Fuels. 38, 10, p. 8649–8660 12 p.

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Conduction Band Tuning by Controlled Alloying of Fe into Cs₂AgBiBr₆ Double Perovskite Powders

Jöbsis, H. J., Fykouras, K., Reinders, J. W. C., van Katwijk, J., Dorresteijn, J. M., Arens, T., Vollmer, I., Muscarella, L. A., Leppert, L. & Hutter, E. M., 9 Dec 2024, In: Advanced Functional Materials. 34, 50, 202306106.

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Correction: Unravelling potential reaction intermediates during catalytic pyrolysis of polypropylene with microscopy and spectroscopy

Vollmer, I., Jenks, M., Rejman, S., Meirer, F., Gurinov, A., Baldus, M. & Weckhuysen, B., 10 Apr 2024, In: Catalysis Science & Technology. 14, 1 p., 2305.

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Da Vinci Project: Educating Sustainability Change-Makers with Transdisciplinary Challenge-Based Learning and Design Thinking

Sluijs, F., Uijl, S., Vogt, E. & Weckhuysen, B. M., 8 Oct 2024, In: Journal of Chemical Education. 101, p. 4161-4172 12 p.

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Effect of Ag Addition to Au Catalysts for the Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid

de Boed, E. J. J., Nolten, H. L., Masoud, N., Vogel, R., Wang, F., Xu, Z., Doskocil, E. J., Donoeva, B. & de Jongh, P. E., 24 Jun 2024, In: ChemCatChem. 16, 12, e202301436.

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Ethylene Polymerization over Metal-Organic Framework-Supported Zirconocene Complexes

Wu, Y., Dorresteijn, J. & Weckhuysen, B., 29 May 2024, In: ACS Catalysis. 14, 11, p. 9093-9103 11 p.

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Exploring the 3D printing of molybdenum carbide-based catalysts for the reverse water gas shift reaction: A multi scale study

Pajares, A., Andrade-Arvizu, J., Jain, D., Monai, M., Lefevere, J., de la Piscina, P. R., Homs, N. & Michielsen, B., 15 Feb 2024, In: Chemical Engineering Journal. 482, p. 1-12 12 p., 149048.

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Fluctuations in the Photoluminescence Excitation Spectra of Individual Semiconductor Nanocrystals

Keitel, R. C., Brechbühler, R., Cocina, A., Antolinez, F. V., Meyer, S. A., Vonk, S. J. W., Rojo, H., Rabouw, F. T. & Norris, D. J., 9 May 2024, In: Journal of Physical Chemistry Letters. 15, 18, p. 4844-4850 7 p.

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Fluorescent-Probe Characterization for Pore-Space Mapping with Single-Particle Tracking

González, R. M., Maris, J. J. E., Wagner, M., Ganjkhanlou, Y., Bomer, J. G., Werny, M. J., Rabouw, F. T., Weckhuysen, B. M., Odijk, M. & Meirer, F., 22 Jan 2024, In: Angewandte Chemie-International Edition. 63, 4, e202314528.

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Green Additives in Chitosan-based Bioplastic Films: Long-term Stability Assessment and Aging Effects

Schnabl, K. B., Mandemaker, L. D. B., Ganjkhanlou, Y., Vollmer, I. & Weckhuysen, B. M., 8 Jul 2024, In: ChemSusChem. 17, 13, 9 p., e202301426.

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Halide Mixing in Cs₂AgBi(I_xBr_1-x)₆ Double Perovskites: A Pathway to Tunable Excitonic Properties

Biega, R. I., Jöbsis, H. J., Gijsberg, Z., Hüskens, M., Hutter, E. M. & Leppert, L., 2024, In: Journal of Physical Chemistry C. 128, 35, p. 14767-14775 9 p.

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Hydrodesulfurization of methanethiol over Co-promoted MoS2 model catalysts

Prabhu, M., Louwen, J., Vogt, E. & Groot, I., 21 Aug 2024, In: Nature Communications. 15, 1, 7170.

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Interrogation of Oxidative Pulsed Methods for the Stabilization of Copper Electrodes for CO<sub>2</sub> Electrolysis

Kok, J., de Ruiter, J., van der Stam, W. & Burdyny, T., 5 Jul 2024, In: Journal of the American Chemical Society. 146, 28, p. 19509-19520 12 p.

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Luminescence Thermometry Probes Local Heat Effects at the Platinum Electrode Surface during Alkaline Water Electrolysis

Jacobs, T. S., Park, S., Schönig, M., Weckhuysen, B. M., Koper, M. T. M. & van der Stam, W., Jun 2024, In: ACS Energy Letters. 9, 7, p. 3335-3341 7 p.

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Mechanistic Insights in the Catalytic Hydrogenation of CO₂ over Pt Nanoparticles in UiO-67 Metal-Organic Frameworks

Pulumati, S. H., Sannes, D. K., Jabbour, C. R., Mandemaker, L. D. B., Weckhuysen, B. M., Olsbye, U., Nova, A. & Skúlason, E., 10 Jan 2024, In: ACS Catalysis. 14, 1, p. 382 - 394 13 p.

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Metal-organic frameworks combined with mid-infrared spectroscopy for the trace analysis of phosphates in water

Frank, F., Baumgartner, B. & Lendl, B., 15 Jan 2024, In: Sensors and Actuators B: Chemical. 399, p. 1-8 9 p., 134778.

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Migration and emission characteristics of metal pollutants in fluid catalytic cracking (FCC) process

Bian, J., Wang, B., Niu, X., Zhao, H., Ling, H. & Ju, F., 15 Jan 2024, In: Journal of Hazardous Materials. 462, 132778.

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Molecular Accessibility and Diffusion of Resorufin in Zeolite Crystals

Maris, J. J. E., Parker, L. A., Stanciakova, K., Nikolopoulos, N., Berendsen, K. M. H., van Blaaderen, A., Meirer, F., Rabouw, F. T. & Weckhuysen, B. M., 2 Jan 2024, In: Chemistry-A European Journal. 30, 1, e202302553.

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Molecular structure and composition elucidation of an industrial humin and its fractions

Constant, S., Lancefield, C., Vogelzang, W., Purushothaman, R., Frissen, A., Houben, K., de Peinder, P., Baldus, M., Weckhuysen, B., van Es, D. & Bruijnincx, P., Jul 2024, In: Green Chemistry. 26, 13, p. 7739-7751 13 p.

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Operando UV-Vis diffuse reflectance spectroscopy insights into the methane dehydroaromatization reaction over Mo/H-ZSM-5 catalysts

Haben, S., Kromwijk, J. J. G., Vollmer, I. & Weckhuysen, B. M., Aug 2024, In: Journal of Catalysis. 436, 9 p., 115619.

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Oxidative Conversion of Polyethylene Towards Di-Carboxylic Acids: A Multi-Analytical Approach

Smak, T. J., de Peinder, P., Van der Waal, J. C., Altink, R., Vollmer, I. & Weckhuysen, B. M., 8 Apr 2024, In: ChemSusChem. 17, 7, e202301198.

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Predicting Molecular Weight Characteristics of Reductively Depolymerized Lignins by ATR-FTIR and Chemometrics

Riddell, L. A., de Peinder, P., Polizzi, V., Vanbroekhoven, K., Meirer, F. & Bruijnincx, P. C. A., 10 Jun 2024, In: ACS Sustainable Chemistry and Engineering. 12, 23, p. 8968–8977 10 p.

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Rapid Lignin Thermal Property Prediction through Attenuated Total Reflectance-Infrared Spectroscopy and Chemometrics

Riddell, L. A., Lindner, J. P. B., de Peinder, P., Meirer, F. & Bruijnincx, P. C. A., 8 May 2024, In: ChemSusChem. 17, 9, 10 p., e202301464.

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Surface-Activated Mechano-Catalysis for Ambient Conversion of Plastic Waste

Hergesell, A. H., Baarslag, R. J., Seitzinger, C. L., Meena, R., Schara, P., Tomović, Ž., Li, G., Weckhuysen, B. M. & Vollmer, I., 25 Sept 2024, In: Journal of the American Chemical Society. 146, 38, p. 26139-26147 9 p.

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Surface Carbon Formation and its Impact on Methane Dry Reforming Kinetics on Rhodium-based Catalysts by Operando Raman Spectroscopy

Colombo, R., Moroni, G., Negri, C., Delen, G., Monai, M., Donazzi, A., Weckhuysen, B. M. & Maestri, M., 11 Nov 2024, In: Angewandte Chemie-International Edition. 63, 46, 9 p., e202408668.

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Tailoring the facet distribution on copper with chloride

Couce, P. M., Madsen, T. K., Plaza-Mayoral, E., Kristoffersen, H. H., Chorkendorff, I., Dalby, K. N., van der Stam, W., Rossmeisl, J., Escudero-Escribano, M. & Sebastian-Pascual, P., 31 Jan 2024, In: Chemical Science. 15, 5, p. 1714-1725 12 p.

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The Coking of a Solid Catalyst Rationalized with Combined Raman and Fluorescence Lifetime Microscopy

Vogel, R., Versluis, C., Frijsen, R., Prins, P. T., Vogt, E. T. C., Rabouw, F. T. & Weckhuysen, B. M., 1 Oct 2024, In: Angewandte Chemie-International Edition. 63, 40, e202409503.

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The refinery of the future

Vogt, E. T. C. & Weckhuysen, B. M., 8 May 2024, In: Nature. 629, 8011, p. 295-306 12 p.

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Thermodynamic limits of the depolymerization of poly(olefin)s using mechanochemistry

Chang, Y., Nguyen, V. S., Hergesell, A. H., Seitzinger, C. L., Meisner, J., Vollmer, I., Schork, F. J. & Sievers, C., 1 Nov 2024, In: RSC mechanochemistry. 1, 5, p. 504-513 10 p.

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Tuning the Optical and Structural Properties of Halide Perovskite by PbS Quantum Dot Additive Engineering for Enhanced Photovoltaic Performances

Salim, K. M. M., Muscarella, L. A., Schuringa, I., Miranda Gamboa, R. A., Torres, J., Echeverría-Arrondo, C., Gualdrón-Reyes, A. F., Rodriguez-Pereira, J., Rincon, M. E., Ehrler, B., Mora-Seró, I. & Masi, S., Mar 2024, In: Solar RRL. 8, 5, 2300892.

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Unravelling potential reaction intermediates during catalytic pyrolysis of polypropylene with microscopy and spectroscopy

Vollmer, I., Jenks, M. J. F., Rejman, S., Meirer, F., Gurinov, A., Baldus, M. & Weckhuysen, B. M., 11 Jan 2024, In: Catalysis Science and Technology. 14, p. 894-902 9 p.

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Utilizing operando catalyst regeneration to uncover insights in the methanol-to-hydrocarbons process

van Vreeswijk, S. H., Parker, L. A., Sanderse, A. T., Oord, R., Meirer, F. & Weckhuysen, B. M., 21 Nov 2024, In: Chem Catalysis. 4, 11, 101134.

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X-ray standing wave characterization of the strong metal–support interaction in Co/TiO_x model catalysts

Tiwari, A., Monai, M., Matveevskii, K., Yakunin, S. N., Mandemaker, L. D. B., Tsvetanova, M., Goodwin, M. J., Ackermann, M. D., Meirer, F. & Makhotkin, I. A., 1 Apr 2024, In: Journal of Applied Crystallography. 57, Pt 2, p. 481-491 11 p.

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Inorganic Chemistry and Catalysis

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